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PERFLUORO COPOLYMERS OF TETRAFLUOROETHYLENE AND PERFLUORO ALKYL VINYL ETHERS

机译:四氟乙烯和全氟烷基乙烯基醚的全氟共聚物

摘要

In preparing a fluorinated thermoplastic with good flex life, high thermal conductivity and low average spherolite diameter from tetrafluoroethylene and perfluoro n-alkyl vinyl ether, perfluoro 2-propoxyalkyl vinyl ether is additionally incorporated into the fluorinated thermoplastic. A semicrystalline, thermoplastically processable copolymer is prepared, made from units of the tetrafluoroethylene, from 2 to 10 % by weight of units of perfluoro n-propyl vinyl ether and from 0.1 to 6 % by weight of units of perfluoro 2-propoxypropyl vinyl ether. The novel copolymer preferably contains fewer than 70 unstable end groups per 106 carbon atoms, has thermal conductivity of at least 0.19 W/mK at 23 DEG C and has a smooth surface with an average spherolite diameter of 5 mu m. The novel terpolymer is suitable for extrusion of hose, in particular for heat exchangers, and also for ultrahigh-purity applications.
机译:在由四氟乙烯和全氟正烷基乙烯基醚制备具有良好挠曲寿命,高导热率和低平均球晶直径的氟化热塑性塑料时,将全氟2-丙氧基烷基乙烯基醚另外掺入氟化热塑性塑料中。由四氟乙烯的单元,2至10重量%的全氟正丙基乙烯基醚单元和0.1至6重量%的全氟2-丙氧基丙基乙烯基醚单元制备半结晶的可热塑性加工的共聚物。该新型共聚物优选每10 6个碳原子含有少于70个不稳定端基,在23℃下具有至少0.19W / mK的导热率,并且具有光滑的表面且平均球晶直径<5μm。新型三元共聚物适用于软管的挤出,特别是用于热交换器,也适用于超高纯应用。

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