首页> 外国专利> Hydrous polyolefin resin composition, pre-expanded particles, their preparation and foamed molded article comprising the same

Hydrous polyolefin resin composition, pre-expanded particles, their preparation and foamed molded article comprising the same

机译:含水聚烯烃树脂组合物,预发泡颗粒,其制备方法和包含该组合物的发泡模塑制品

摘要

A hydrous resin composition suitable for the preparation of a polyolefin resin preliminary foamed particle containing a polyolefin resin and a hydrophilic polymer and having a water content of 1 to 50% by weight is preliminarily foamed and the hydrous resin composition is preliminarily foamed, and the foaming factor of 5 to Polyolefin resin preliminary foam particles with an independent bubble rate of 80 to 100% and an average bubble diameter of 50 to 500. Mu. M. The preliminary foamed particles are formed by dispersing resin particles comprising polyolefin resin and hydrophilic polymer in a closed container in a closed container to form a dispersion solution, and heating them to a temperature above the softening temperature of the polyolefin resin, and water content. As the water-soluble resin particles having a rate of 1 to 50% by weight, and the aqueous dispersion of the aqueous dispersion is released from the closed container into an atmosphere of less pressure than the internal pressure of the closed container to foster the water containing resin particles, it is possible to manufacture without using the volatile blowing agent. The release of the dispersion from the closed vessel is carried out in the closed vessel.When the internal pressure is applied to 25 to 75 kg / cm. Sup. 2 g, the preliminary foaming particles capable of providing a high foaming magnification foam having good physical properties can be obtained.
机译:预先发泡适用于制备包含聚烯烃树脂和亲水性聚合物并且水含量为1至50重量%的聚烯烃树脂预发泡颗粒的含水树脂组合物,并且将所述含水树脂组合物预先发泡,并且发泡聚烯烃树脂预发泡颗粒的膨胀系数为5,独立气泡率为80至100%,平均气泡直径为50至500。 M.通过将包含聚烯烃树脂和亲水性聚合物的树脂颗粒分散在密闭容器中的密闭容器中以形成分散溶液,并将它们加热至高于聚烯烃树脂的软化温度和水含量的温度而形成预发泡颗粒。 。由于水溶性树脂颗粒的重量比为1%至50%,并且水分散体的水分散体从密闭容器中释放到压力小于密闭容器内部压力的气氛中,从而积聚水由于包含树脂颗粒,因此可以在不使用挥发性发泡剂的情况下进行制造。从密闭容器中释放分散液是在密闭容器中进行的。当内部压力施加在25至75 kg / cm时。燮。 2g,可以获得能够提供具有良好物理性能的高发泡倍率泡沫的预发泡颗粒。

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