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Blends of fatty acids with improved cold stability, containing comb polymers, and use thereof in fuel oils

机译:具有改善的冷稳定性的脂肪酸共混物,包含梳形聚合物,及其在燃料油中的用途

摘要

Cold-stabilized fatty acid composition comprises: (a) a mixture of saturated and unsaturated mono- or di-carboxylic acids with 6-50 carbon atoms; and (b) a copolymer comprising dicarboxylic acid ester, anhydride or imide units and (meth)acrylate or vinyl ester units. Cold-stabilized fatty acid composition comprises: (a) 10-99.9 wt.% of a fatty acid mixture comprising 1-99 wt.% saturated and 1-99 wt.% unsaturated mono- or di-carboxylic acids with 6-50 carbon (C) atoms; and (b) 0.01-90 wt.% of a copolymer comprising 40-60 mole% units of formula (Ia) or (Ib), 40-60 mole% units of formula (II) and 0-20 mole% of poly(3-5C olefin) units containing a total of 35-350 C atoms. [Image] -H 2C-CR 2R 3- (II) X : O or NR 1; a, b : 0 or 1; a+b : 1; R 110-40C alkyl or alkenyl or alkoxylated 1-30C alkyl with 1-100 alkoxy units; R 2H or Me; R 3OCOR 4 or COOR 4; R 41-24C alkyl. Independent claims are also included for the following: (1) A solution comprising the fatty acid composition and 1-80 wt.% organic solvent. (2) Fuel oils comprising a middle distillate with a sulfur content of up to 0.05 wt.% and either the fatty acid composition or solution (1).
机译:冷稳定的脂肪酸组合物包含:(a)具有6-50个碳原子的饱和和不饱和一元或二元羧酸的混合物; (b)包含二羧酸酯,酸酐或酰亚胺单元和(甲基)丙烯酸酯或乙烯基酯单元的共聚物。冷稳定的脂肪酸组合物包含:(a)10-99.9 wt。%的脂肪酸​​混合物,该脂肪酸混合物包含1-99 wt。%的饱和脂肪酸和1-99 wt。%的具有6-50碳原子的不饱和一元或二元羧酸(C)原子; (b)0.01-90 wt。%的共聚物,包含40-60摩尔%的式(Ia)或(Ib)单元,40-60摩尔%的式(II)单元和0-20摩尔%的聚(含有3-5个碳原子的3-5C烯烃)单元。 [图像] -H 2C-CR 2> R 3>-(II)X:O或NR 1>; a,b:0或1; a + b:1; R 1> 10-40C的烷基或链烯基或具有1-100个烷氧基单元的烷氧基化的1-30C烷基; R 2> H或Me; R 3> OCOR 4>或COOR 4>; R 4> 1-24C烷基。还包括以下方面的独立权利要求:(1)包含脂肪酸组合物和1-80wt。%的有机溶剂的溶液。 (2)燃料油,其包含硫含量高达0.05重量%的中间馏分和脂肪酸组合物或溶液(1)。

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