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Mesoporous carbon composite, method of preparing the same, and fuel cell using the mesoporous carbon composite

机译:介孔碳复合材料,其制备方法以及使用该介孔碳复合材料的燃料电池

摘要

A mesoporous carbon composite includes mesoporous carbon having mesopores; a conductive polymer coated on only an outer surface of the mesoporous carbon; and an organic electrolyte comprising a lithium salt and an organic solvent. The mesoporous carbon composite may be prepared by impregnating an ordered mesoporous silica (OMS) with a carbon precursor mixture comprising a carbon precursor, an acid, and a solvent; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; mixing the OMS-carbon composite with a monomer that forms a conductive polymer and a solvent to provide a surface of the OMS-carbon composite with the monomer that forms a conductive polymer; polymerizing the monomer to obtain a conductive polymer-coated OMS-carbon composite; removing the OMS from the conductive polymer-coated OMS-carbon composite to obtain a conductive polymer-coated mesoporous carbon; and doping the conductive polymer-coated mesoporous carbon with an organic electrolyte comprising a lithium salt and an organic solvent to form the mesoporous carbon composite. A supported catalyst contains the mesoporous carbon composite, and a fuel cell uses an electrode containing the mesoporous carbon composite.
机译:中孔碳复合材料包括具有中孔的中孔碳;和仅涂覆在中孔碳的外表面上的导电聚合物;以及包含锂盐和有机溶剂的有机电解质。介孔碳复合材料可以通过用包含碳前体,酸和溶剂的碳前体混合物浸渍有序介孔二氧化硅(OMS)来制备。对浸渍的OMS进行热处理和碳化,以形成OMS-碳复合物;将OMS-碳复合物与形成导电聚合物的单体和溶剂混合,以使OMS-碳复合物的表面与形成导电聚合物的单体混合;使单体聚合以获得导电聚合物涂覆的OMS-碳复合物;从导电聚合物涂覆的OMS-碳复合物中除去OMS,以获得导电聚合物涂覆的中孔碳;并用包含锂盐和有机溶剂的有机电解质掺杂涂覆有导电聚合物的介孔碳,以形成介孔碳复合材料。负载型催化剂包含中孔碳复合物,并且燃料电池使用包含中孔碳复合物的电极。

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