首页> 外国专利> METHOD FOR PREPARING CARBONIZED MESOPOROUS BLOCK COPOLYMER PARTICLE CATALYST COMPRISING CARBONIZED MESOPOROUS BLOCK COPOLYMER PARTICLE PREPARED BY THE SAME AND CATHODE MATERIALS OF FUEL CELL COMPRISING THE CATALYST

METHOD FOR PREPARING CARBONIZED MESOPOROUS BLOCK COPOLYMER PARTICLE CATALYST COMPRISING CARBONIZED MESOPOROUS BLOCK COPOLYMER PARTICLE PREPARED BY THE SAME AND CATHODE MATERIALS OF FUEL CELL COMPRISING THE CATALYST

机译:包含由包含燃料的燃料电池的相同和阴极材料制备的碳化亚甲基嵌段共聚物颗粒的方法

摘要

The present invention relates to a method for producing carbonized mesoporous block copolymer particles, a catalyst comprising the carbonized mesoporous block copolymer particles, and a fuel cell negative electrode material comprising the catalyst, one embodiment of the present invention A method for producing carbonized mesoporous block copolymer particles according to an example includes: preparing a dispersion phase and a continuous phase to form emulsions; Forming an emulsion droplet by passing the emulsion through pores of a Shirasu porous glass (SPG) membrane; Separating the droplets formed on the membrane surface into a continuous phase; Evaporating the solvent in the emulsion to form block copolymer (BCP) particles; Forming a porous hyper-block copolymer particle by hyper-crosslinking and selectively etching the block copolymer particle; And doping and then carbonizing the porous hyper block copolymer particles with metal atoms to form metal atom/carbonized block copolymer particles. And thermally reducing the metal atom/carbonized block copolymer particles by dissolving them in a mixture containing a platinum precursor.
机译:碳化中孔嵌段共聚物粒子的制造方法,包含该碳化中孔嵌段共聚物粒子的催化剂,以及包含该催化剂的燃料电池负极材料,本发明的一个实施方式涉及一种碳化中孔嵌段共聚物的制造方法。根据一个实例的颗粒包括:制备分散相和连续相以形成乳液;和通过使乳剂通过Shirasu多孔玻璃(SPG)膜的孔形成乳剂液滴;将在膜表面上形成的液滴分离为连续相;蒸发乳液中的溶剂以形成嵌段共聚物(BCP)颗粒;通过超交联并选择性地蚀刻该嵌段共聚物颗粒形成多孔的超嵌段共聚物颗粒;然后用金属原子掺杂然后碳化多孔的超嵌段共聚物颗粒以形成金属原子/碳化的嵌段共聚物颗粒。并且通过将金属原子/碳化的嵌段共聚物颗粒溶解在包含铂前体的混合物中来热还原。

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