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RECYCLING OF WASTE EXPANDED POLYSTYRENE FOAMS TO GIVE PRODUCTS WHICH MAY BE RE-EXPANDED

机译:回收废发泡聚苯乙烯泡沫以提供可以重新膨胀的产品

摘要

The invention relates to a method for the production of re-expandable polystyrene by material recycling of waste expanded polystyrenes. The expanded polystyrene waste is dissolved in a solvent, selected from di-(lower alkylene)glycol di-(lower alkyl) ethers, where lower alkyl = straight- or branched-chain C1 - C12 alkyl, mono- or di-carboxylate di-(lower alkyl) esters with a straight- or branched- carboxylate chain length of C1 - C12, where lower alkyl has the meaning given for the glycol ether, THF, ketones, mixtures of the above solvents and mixtures of said solvents with ethylene carbonate, propylene carbonate, cyclohexane and/or rapeseed oil methyl ester. The polystyrene solution is precipitated using a precipitating agent which has a polarity lower than the employed solvent and the precipitated polystyrene is optionally partly dried, such that the blowing agent incorporated in the polystyrene is not removed. Finally the precipitated polystyrene can be re-expanded by means of a heat-carrier.
机译:本发明涉及一种通过废膨胀的聚苯乙烯的材料回收来生产可再膨胀的聚苯乙烯的方法。将膨胀的聚苯乙烯废料溶解在选自二-(低级亚烷基)二醇二-(低级烷基)醚的溶剂中,其中低级烷基=直链或支链C1-C12烷基,单或二羧酸二-酯。具有直链或支链羧酸酯链长为C1-C12的(低级烷基)酯,其中低级烷基具有乙二醇醚,THF,酮,上述溶剂的混合物以及所述溶剂与碳酸亚乙酯的混合物的含义,碳酸亚丙酯,环己烷和/或菜籽油甲酯。使用极性低于所用溶剂的沉淀剂使聚苯乙烯溶液沉淀,并且任选地将沉淀的聚苯乙烯部分地干燥,使得不除去引入聚苯乙烯中的发泡剂。最后,沉淀的聚苯乙烯可以借助于热载体而再次膨胀。

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