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Preparation of Styrene-Acrylate Emulsion (SAE) Latex by Recycling Waste Expandable Polystyrene Foam

机译:通过回收废弃物可膨胀聚苯乙烯泡沫制备苯乙烯 - 丙烯酸酯乳液(SAE)乳液

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This study explored recycling waste expandable polystyrene (EPS) foam to produce styrene-acrylate emulsion (SAE) latex. EPS substituted styrene ranging from 10% to 50%. Flocculation was observed when EPS content is >40%. Solid content and gel rate confirmed this observation. Particle size distribution showed particle size increased and its distribution broadened as EPS content increased. This may probably due to the viscosity increment of the emulsion droplets when EPS content increase and lead to increment of the droplets size and the emulsion gradually lost stability, therefore the solid content and gel rate increased. Hence stable SAE can be produced with EPS <30%. Monomer conversion results showed EPS did not affect the final monomer conversion percentage. IR results showed that incorporation of EPS did not alter the chemical composition of the SAE product. The presence of EPS lowered the monomer conversion rate and but did not save the polymerization time.
机译:本研究探索了回收废弃物可膨胀聚苯乙烯(EPS)泡沫以产生苯乙烯 - 丙烯酸酯乳液(SAE)乳胶。 EPS取代苯乙烯,范围为10%至5​​0%。当EPS含量> 40%时,观察到絮凝。固体含量和凝胶率证实了这种观察。粒度分布显示粒度增加,随着EPS含量的增加,其分布扩大。这可能可能是由于乳液液滴的粘度增加,当EPS含量增加并导致液滴尺寸的增量和乳液逐渐丧失稳定性时,因此固体含量和凝胶速率增加。因此,可以使用EPS <30%生产稳定的SAE。单体转化结果显示EPS不影响最终的单体转化率。 IR结果表明,EPS的掺入没有改变SAE产品的化学成分。 EPS的存在降低了单体转化率,但不保存聚合时间。

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