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POLYIMIDE FOR PRODUCING CAST-ON-COPPER LAMINATE AND METHOD FOR PRODUCING THEREOF

机译:用于生产铜铸叠层的聚酰亚胺及其制备方法

摘要

Polyimide for producing a copper clad laminate and a manufacturing method for the same are provided to secure favorable dimensional stability, tear resistance, flex resistance, and transparency of the copper clad laminate. The method for manufacturing copper clad laminates for a flexible printed circuit board comprises the steps of: producing a polyamic acid solution by dissolving and reacting aromatic tetracarboxylic dianhydrides and aromatic diamine in a polar aprotic solvent without adding an inorganic filler; applying the polyamic acid solution on a copper foil; and forming a polyimide layer on the copper foil by heating the polyamic acid solution with continuing amidation reaction. The polyimide layer has a thermal expansion coefficient of 10~30ppm/‹C. The aromatic tetracarboxylic dianhydride is at least one selected from a group comprising biphenyl tetracarboxylic dianhydride, pyromellitic dianhydride, and benzophenone tetracarboxylic dianhydride.
机译:提供一种用于生产覆铜层压板的聚酰亚胺及其制造方法,以确保覆铜层压板的良好的尺寸稳定性,抗撕裂性,耐挠性和透明性。用于柔性印刷电路板的覆铜层压板的制造方法包括以下步骤:通过将芳族四羧酸二酐和芳族二胺溶解在极性非质子溶剂中并使之反应而制备聚酰胺酸溶液,而无需添加无机填料;将聚酰胺酸溶液涂覆在铜箔上;通过在连续的酰胺化反应下加热聚酰胺酸溶液,在铜箔上形成聚酰亚胺层。聚酰亚胺层的热膨胀系数为10〜30ppm /℃。芳族四羧酸二酐是选自联苯四羧酸二酐,均苯四甲酸二酐和二苯甲酮四羧酸二酐中的至少一种。

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