A semiconductor device having dual work-function structures, such as dual work-function gate electrodes of transistors. In the preferred embodiment in which NMOS and PMOS transistors are formed on a semiconductor device, the transistors are initially formed with a dummy gate electrode and a dummy dielectric layer. The dummy gate electrode and dummy dielectric layers are removed. A gate dielectric layer and a first electrode layer are formed. A nitridation process is performed on the NMOS transistor to reduce the work function of the gate electrode. A second electrode layer is then formed on the first electrode layer.
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