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A PROCESS FOR PREPARATION OF A BARIUM TITANATE BASED COMPOSITION HAVING MEDIUM DIELECTRIC CONSTANT AND TEMPERATURE STABILITY
A PROCESS FOR PREPARATION OF A BARIUM TITANATE BASED COMPOSITION HAVING MEDIUM DIELECTRIC CONSTANT AND TEMPERATURE STABILITY
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机译:具有介电常数和温度稳定性的钛酸钡基组合物的制备方法
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摘要
The present invention provides a process for preparation of a barium titanate based composition having medium dielectric constant and temperature stability comprising adding 0.3 - 2.0 wt.% of barium titanate ( BaTi03) fluxes containing Li2C2O4, Li2B4O7, H3BO3 and Bi2O3 and Bi2O3 to BaTiO3 powder; adding 0.75 - 2.0 wt.% (BaTiO3) grain growth inhibitors and Curie peak suppressors containing Nb2O5, Bi2 (SnO3)3 and Bi4Ti3O12 to BaTio3 powder ;adding 0.03- 0.2 wt.% (of BaTiO3) acceptor dopants containing MnO2, NiO, CuO, V2O5, and CO3O4 to BaTiO3 powder; mixing the compositions in a ball mill ( agate grinding medium) with 60 - 80, wt% ( of powder mix) % and distilled water for 10 - 20 h; drying the mixture at 100-150°C in an oven for 2 -4 h; calcining the mixture at 600-800°C for 5-10 h ; dry grinding of the calcined powder in a ball mill (agate grinding media) for 5-10 h. to obtain the said composition.
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机译:本发明提供了一种制备具有中等介电常数和温度稳定性的钛酸钡基组合物的方法,该方法包括向BaTiO 3粉末中添加0.3-2.0wt。%的包含Li 2 C 2 O 4,Li 2 B 4 O 7,H 3 BO 3和Bi 2 O 3和Bi 2 O 3的钛酸钡(BaTiO 3)焊剂。向BaTio3粉中添加0.75-2.0 wt。%(BaTiO3)晶粒生长抑制剂和居里峰抑制剂,其中包含Nb2O5,Bi2(SnO3)3和Bi4Ti3O12;向其中添加0.03- 0.2 wt。%(BaTiO3)的受体掺杂剂,其中包含MnO2,NiO,CuO ,V2O5和CO3O4转化为BaTiO3粉末;在球磨机(玛瑙研磨介质)中将组合物与60-80重量%(粉末混合物)%和蒸馏水混合10-20小时;将混合物在烘箱中在100-150℃下干燥2-4小时;将混合物在600-800°C下煅烧5-10小时;将煅烧后的粉末在球磨机(玛瑙研磨介质)中干磨5-10小时。获得所述组合物。
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