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Method for producing a water-soluble (meth) acrylic acid polyalkylene glycol ester

机译:水溶性(甲基)丙烯酸聚亚烷基二醇酯的制造方法

摘要

PROBLEM TO BE SOLVED: To provide a method for easily and inexpensively producing water-soluble polyalkylene glycol (meth)acrylic ester of high purity with reduced impurity content through transesterification reaction by solving the problems on the conventional transesterification reaction in which a basic catalyst, for example, an alkali metal hydroxide, an alkaline earth metal hydroxide, an alkali metal alkoxide is used as a catalyst but these processes are accompanied by a large amount of by-products and less prone to attain high reactivity.;SOLUTION: In this method for producing water-soluble polyalkylene glycol (meth)acrylic ester, a glycol compound and a (meth)acrylic ester are allowed to react with each other by using titanium alkoxide and/or zirconium alkoxide as a transesterification, then the reaction mixture is treated with water to separate the insoluble matter.;COPYRIGHT: (C)2005,JPO&NCIPI
机译:解决的问题:提供一种通过酯交换反应,通过解决常规的酯交换反应的问题,该方法通过碱交换反应容易且廉价地生产具有降低的杂质含量的高纯度的水溶性聚亚烷基二醇(甲基)丙烯酸酯的方法。例如,碱金属氢氧化物,碱土金属氢氧化物,碱金属醇盐用作催化剂,但这些过程伴随着大量的副产物,并且不易获得高反应活性。制备水溶性聚亚烷基二醇(甲基)丙烯酸酯,二醇化合物和(甲基)丙烯酸酯通过使用烷氧基钛和/或烷氧基锆进行酯交换反应彼此反应,然后将反应混合物用水处理分离不溶物。版权所有:(C)2005,日本特许厅

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