首页> 外国专利> POLYLACTIC ACID - CLAY NANOCOMPOSITES BY LACTIDE POLYMERIZATION IN CLAYS

POLYLACTIC ACID - CLAY NANOCOMPOSITES BY LACTIDE POLYMERIZATION IN CLAYS

机译:粘土中丙交酯聚合形成的聚丙烯酸-粘土纳米复合材料。

摘要

The invention relates to process for preparing a polylactic acid-clay nanocomposite the process comprising melt polymerization of the lactide intercalated in an organically modified clay in the presence of a catalyst to form a prepolymer-clay nanocomposite having reactive end groups, the catalyst being in the form of a complex, the complex comprising a lactide, a metal-oxo compound and a lactic acid oligomer and the clay being present in an amount up to approximately 10% by weight, the residual lactide after the melt polymerization being removed by heating the prepolymer-clay nanocomposite in the temperature range of 98°C to a temperature lower than melting point of the prepolymer and solid state polymerization of the prepolymer-clay nanocomposite. The process of the present invention yield polylactic acid-clay nanocomposites having a molecular weight from around 10,000 to 20,000 and crystallinity in the range of 25 to 95%.
机译:本发明涉及一种制备聚乳酸-粘土纳米复合材料的方法,该方法包括在催化剂的存在下,将插入在有机改性粘土中的丙交酯熔融聚合,以形成具有反应性端基的预聚物-粘土纳米复合材料。络合物的形式,该络合物包含丙交酯,金属-氧代化合物和乳酸低聚物,并且粘土以至多约10重量%的量存在,通过加热预聚物除去熔融聚合后的残留丙交酯-粘土纳米复合材料在98℃至低于预聚物熔点的温度范围内进行预聚物-粘土纳米复合材料的固态聚合。本发明的方法产生了分子量为约10,000至20,000且结晶度为25至95%的聚乳酸粘土纳米复合材料。

著录项

  • 公开/公告号IN2007MU00679A

    专利类型

  • 公开/公告日2008-11-28

    原文格式PDF

  • 申请/专利权人

    申请/专利号IN679/MUM/2007

  • 发明设计人 NANAVATI HEMANT;KATIYAR VIMAL;

    申请日2007-04-04

  • 分类号C08K3/04;

  • 国家 IN

  • 入库时间 2022-08-21 19:27:23

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