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Alkaline glasses with modified surfaces and method for producing same

机译:具有改性表面的碱性玻璃及其制造方法

摘要

The invention concerns alkaline glasses with modified glass surfaces. The technical object of the invention is to stabilize the modified glass surface so that reverse sodium diffusion out of the volume is substantially avoided even at elevated temperatures and in particular in the case of post-treatment procedures using a flame. Surprisingly it was found that a modified glass surface of an alkaline glass is substantially resistant to reverse sodium diffusion from the volume at elevated temperatures if the chemism within the surface has an aluminum concentration which is markedly increased in relation to the volume. The cause can be the very high level of negative formation enthalpy of albite phases. The process according to the invention is characterized in that the surface of said glasses is brought into contact with elevated levels of aluminum concentration and is subjected to a heat treatment.
机译:本发明涉及具有改性玻璃表面的碱性玻璃。本发明的技术目的是稳定改性的玻璃表面,从而即使在升高的温度下,尤其是在使用火焰的后处理程序的情况下,也基本上避免了钠的反向扩散。令人惊讶地发现,如果碱玻璃的改性玻璃表面中的化学性质相对于该体积显着增加,则在高温下该玻璃的改性玻璃表面基本上抵抗钠从该体积反向扩散。原因可能是钠长石相的负形成焓很高。根据本发明的方法的特征在于,使所述玻璃的表面与升高的铝浓度水平接触并进行热处理。

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