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BRIDGED METALLOCENE COMPOUND, OLEFIN POLYMERIZATION CATALYST USING THE COMPOUND AND ETHYLENE POLYMER OBTAINED BY USING THE CATALYST

机译:桥接茂金属化合物,使用该化合物的烯烃聚合催化剂和使用该催化剂获得的乙烯聚合物

摘要

It relates to a metallocene compound useful as an olefin polymerization catalyst or catalyst component, and an olefin polymerization method using an olefin polymerization catalyst containing the metallocene compound. More particularly, it relates to an olefin polymerization catalyst capable of producing an olefin polymer having a high melt tension, excellent mechanical strength and excellent particle properties with a high polymerization activity, an olefin polymerization method using this catalyst, an ethylene polymer which is obtained by the polymerization method and is excellent in moldability, easy openability, and particularly excellent in mechanical strength as compared with conventionally known ethylene polymers, and a thermoplastic resin composition containing the ethylene polymer. More particularly, it provides a molded article and a film formed from the ethylene polymer or the thermoplastic resin composition containing the ethylene polymer, and a laminate film comprising the film. It provides an olefin polymer which shows little neck-in in T-die molding, does not cause take-off surging, is particularly excellent in mechanical strength, and has a large number of long-chain branches caused by simultaneously inducing production of a macromonomer as a source of long-chain branches and repolymerization of the produced macromonomer in the coexistence of a single type or plural types of bridged metallocene compounds including a group derived from a cyclopentadienyl group having a different structure in the same polymerization system, an olefin polymerization catalyst and a polymerization method capable of efficiently producing the olefin polymer.
机译:本发明涉及用作烯烃聚合催化剂或催化剂组分的金属茂化合物,以及使用含有该金属茂化合物的烯烃聚合催化剂的烯烃聚合方法。更具体地,涉及一种能够以高聚合活性生产具有高熔体张力,优异的机械强度和优异的颗粒性质的烯烃聚合物的烯烃聚合催化剂,使用该催化剂的烯烃聚合方法,通过以下方法获得的乙烯聚合物。与常规的乙烯聚合物和含有该乙烯聚合物的热塑性树脂组合物相比,该聚合方法具有优异的成型性,易开封性,特别是机械强度优异。更特别地,其提供了由乙烯聚合物或包含乙烯聚合物的热塑性树脂组合物形成的模制品和膜,以及包含该膜的层压膜。它提供了一种烯烃聚合物,该烯烃聚合物在T模头成型中几乎没有缩颈,不会引起脱模,特别是机械强度极好,并且由于同时诱导大分子单体的产生而具有大量的长链分支。作为长链分支的来源和所产生的大分子单体在同一聚合体系中共存的一种或多种桥接金属茂化合物的共聚合,所述茂金属化合物包括衍生自具有不同结构的环戊二烯基的基团的烯烃聚合催化剂以及能够有效地制造烯烃聚合物的聚合方法。

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