Disclosed is a polyisocyanate composition derived from an aliphatic diisocyanate monomer and an alcohol, which satisfies all the conditions below in a state not containing the aliphatic diisocyanate monomer and a solvent. 1) Isocyanurate trimer concentration: 55-95 mass% 2) Number ratio of allophanate groups derived from the alcohol to isocyanurate groups: 1-20% 3) Urethodione dimmer concentration: 2-25 mass% 4) Viscosity at 25°C: 150-800 mPa·s
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