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IMIDAZOLIUM SALTS AND THEIR USE OF THESE IONIC LIQUIDS AS A SOLVENT

机译:咪唑盐及其作为溶剂的这些离子液体的用途

摘要

New 1,2,3- or 1,2,3,4- or 1,2,3,4,5- substituted imidazolium salts and theiruses as solvent in catalysed organic reactions, as well as compositionscontaining them and a transition metal compound. They can be used in thefollowing reactions: telomerisation of conjugated dienes, dimerisation ofolefins, oligomerisation of olefins, polymerization of olefins, alkylation ofolefins, hydrogenations of olefins, olefin metathesis, hydroformylation ofolefins, ring-closing metathesis of olefins, ring-opening metathesispolymerisation of olefins, symmetric or asymmetric epoxidation of olefins(including heteroatom substituted olefins) and cyclopropanation of olefins,condensation reaction, hydrogenation reactions, isomerisation reaction, Suzukicross-coupling reactions, amination reaction, partial oxidation of alkanes,kinetic resolution of racemic mixtures, hydrogenation of imines, hydrogenationof ketones, transfer hydrogenation and hydroxylation of aromatic organiccompounds.
机译:新的1,2,3-或1,2,3,4-或1,2,3,4,5-取代的咪唑鎓盐及其在催化的有机反应中用作溶剂以及组合物包含它们和过渡金属化合物。它们可以用于以下反应:共轭二烯的端粒化,烯烃,烯烃低聚,烯烃聚合,烷基化烯烃,烯烃加氢,烯烃复分解,加氢甲酰化烯烃,烯烃的开环复分解烯烃聚合,烯烃对称或不对称环氧化(包括杂原子取代的烯烃)和烯烃的环丙烷化,缩合反应,氢化反应,异构化反应,铃木交叉偶联反应,胺化反应,烷烃的部分氧化,外消旋混合物的动力学拆分,亚胺的氢化,氢化的合成,芳族有机物的转移加氢和羟基化化合物。

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