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Imidazolium salts and their use as solvents for these ionic liquids

机译:咪唑鎓盐及其作为这些离子液体的溶剂的用途

摘要

New 1,2,3- or 1,2,3,4- or 1,2,3,4,5- substituted imidazolium salts and their uses as solvent in catalyzed organic reactions, as well as compositions containing them and a transition metal compound. They can be used in the following reactions : the telomerisation of conjugated dienes, the dimerisation of olefins, the oligomerisation of olefins, the polymerization of olefins, the alkylation of olefins, the hydrogenation of olefins, the olefin metathesis, the hydroformylation of olefins, the ring-closing metathesis of olefins, the ring-opening metathesis polymerisation of olefins, the symetric or asymetric epoxidation of olefins (including heteroatom substituted olefins) and the cyclopropanation of olefins, the condensation reaction, the hydrogenation reaction, the isomerization reaction, the Suzuki cross-coupling reactions, the amination reaction, the partial oxidation of alkancs, the kinetic resolution of racemic mixtures, the hydrogenation of imines, the hydrogenation of ketones, the transfer hydrogenation and the hydroxylation of aromatic organic compounds.
机译:新的1,2,3-或1,2,3,4-或1,2,3,4,5-取代的咪唑鎓盐及其在催化的有机反应中的溶剂用途,以及含有它们和过渡金属的组合物复合。它们可用于以下反应:共轭二烯的调聚,烯烃的二聚,烯烃的低聚,烯烃的聚合,烯烃的烷基化,烯烃的加氢,烯烃的复分解,烯烃的加氢甲酰化,烯烃的开环复分解,烯烃的开环复分解聚合,烯烃(包括杂原子取代的烯烃)的对称或不对称环氧化和烯烃的环丙烷化,缩合反应,氢化反应,异构化反应,Suzuki交联-偶联反应,胺化反应,链烷烃的部分氧化,外消旋混合物的动力学拆分,亚胺的氢化,酮的氢化,芳族有机化合物的转移氢化和羟基化。

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