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POLYURETHANE COMPOSITION FOR MANUFACTURE OF HOLOGRAPHIC MEDIA, ITS APPLICATION, METHOD FOR HOLOGRAM RECORDING AND UNSATURATED URETANES

机译:用于制造全息介质的聚氨酯组合物,其应用,全息记录方法和不饱和脲

摘要

1. A polyurethane composition for the manufacture of holographic media, comprising a component of the recording monomer a) containing as recording monomers, in terms of the entire composition, at least 10 wt.% Of one or more unsaturated urethanes a) of the formula (I) to (III) ), as well as polymer compounds or the corresponding matrix precursors as a matrix for recording monomers! ! ! ! where R independently in each case is a radiation-curable group, and also! X independently from each other in each case represents a single bond between the groups R and C = O or a linear, branched or cyclic, optionally containing a heteroatom, and / or optionally functionally substituted hydrocarbon residue. ! 2. The polyurethane composition according to claim 1, characterized in that R in the formulas (I) to (III) represents a vinyloxy, acrylate or methacrylate group. ! 3. The polyurethane composition according to claim 1, characterized in that in the formulas (I) to (III), group X in each case is a linear or branched hydroxyalkylene or polyoxyalkylene group. ! 4. The polyurethane composition according to claim 1, characterized in that it contains a recording monomer a) in terms of the total composition in an amount of from 20 to 50 wt.%. ! 5. The polyurethane composition according to claims 1 to 4, characterized in that as forming components for the matrix includes:! isocyanate component b),! isocyanate-reactive component c),! as well as one or more photoinitiators d). ! 6. A method of manufacturing media suitable for recording visual holograms, in which
机译:1.一种用于制造全息照相介质的聚氨酯组合物,其包含记录单体a)的组分,其在整个组合物中包含至少10重量%的一种或多种下式的不饱和氨基甲酸酯a)作为记录单体。 (I)至(III)),以及高分子化合物或相应的基质前体作为记录单体的基质! ! ! !其中R分别独立地是可辐射固化的基团,并且! X在每种情况下彼此独立地表示基团R和C = O之间的单键或直链,支链或环状的,任选地包含杂原子,和/或任选地在功能上被取代的烃残基。 ! 2.根据权利要求1的聚氨酯组合物,其特征在于式(I)至(III)中的R表示乙烯基氧基,丙烯酸酯或甲基丙烯酸酯基团。 ! 3.根据权利要求1或2的聚氨酯组合物,其特征在于在式(I)至(III)中,基团X分别是直链或支链的羟基亚烷基或聚氧化烯基。 ! 4.根据权利要求1的聚氨酯组合物,其特征在于,按总组合物计,其包含记录单体a)的量为20至50重量%。 ! 5.根据权利要求1-4的聚氨酯组合物,其特征在于作为基质的形成组分包括:异氰酸酯组分b),!异氰酸酯反应性组分c),!以及一种或多种光引发剂d)。 ! 6.一种制造适于记录视觉全息图的介质的方法,其中

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