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NANOSTRUCTURED CERAMIC MATRIX COMPOSITE MATERIAL AND METHOD OF PRODUCING SAID MATERIAL

机译:纳米结构陶瓷基复合材料及其制备方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to machine engineering ceramics, particularly ceramic matrix composite material based on silicon carbide and reinforced with carbon fibre. The composite material contains a matrix of reaction-sintered silicon carbide, reinforced with bundles of carbon filaments, separated from the matrix by a barrier layer. The filaments in the bundles are joined to each other by a dense sintered nanosize inter-filament phase which contains carbon, silicon, boron, nitrogen, as well as aluminium and yttrium oxide compounds. The barrier layer and the inter-filament phase do not contain free carbon. The method of producing the composite material involves pre-treatment of the bundles of carbon filaments with a suspension which contains polymer binder and nanoparticles of silicon nitride, aluminium and yttrium oxide compounds and at least one component selected from: boron, silicon, boron or silicon compound. After drying, the fibre mass is saturated with coke-forming binder which contains silicon carbide particles, the workpiece is moulded, the binder is cured, followed by a carbonisation step, synthesis and sintering of the inter-filament phase, and then a step for saturating the workpiece with solutions or melts of coke-forming polymers and silicification.;EFFECT: obtaining material with high characteristic strength and impact viscosity.;8 cl, 1 tbl, 2 dwg
机译:技术领域本发明涉及机械工程陶瓷,特别是基于碳化硅并用碳纤维增强的陶瓷基复合材料。该复合材料包含反应烧结的碳化硅基体,并用碳丝束加固,并通过阻挡层将其与基体隔开。束中的长丝通过包含碳,硅,硼,氮以及铝和氧化钇化合物的致密的烧结纳米级中间丝相相互连接。阻挡层和丝间相不包含游离碳。生产复合材料的方法包括用悬浮液对碳丝束进行预处理,该悬浮液包含聚合物粘合剂和氮化硅,铝和氧化钇化合物的纳米颗粒以及至少一种选自硼,硅,硼或硅的组分复合。干燥后,纤维团被含碳化硅颗粒的焦炭形成的粘合剂浸透,成型工件,固化粘合剂,然后进行碳化步骤,中间丝相的合成和烧结,然后进行用焦炭形成的聚合物的溶液或熔体使工件饱和并硅化;效果:获得具有高特征强度和冲击粘度的材料; 8 cl,1 tbl,2 dwg

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