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AMORPHOUS HYDROUS TITANIUM OXIDE AND SOLID LEWIS ACID CATALYST CONTAINING SAME

机译:相同的非晶态二氧化钛和固体路易斯酸催化剂

摘要

Disclosed are: a novel substance which functions as a solid Lewis acid catalyst in the presence of water; a process for producing the same; use thereof as a solid Lewis acid catalyst; and a method for conducting a chemical reaction in an aqueous solution using the solid Lewis acid catalyst. Amorphous hydrous titanium oxide, which functions as a Lewis acid, can be obtained by subjecting an organotitanium compound which can be hydrolyzed in an aqueous solution to form an oxide to reaction with both water and an acid or base catalyst. This Lewis acid catalyst exhibits excellent effect in various reactions including a reaction of forming hydroxymethylfurfural from glucose.
机译:公开了一种在水存在下起固体路易斯酸催化剂作用的新型物质。生产它的过程;其用作固体路易斯酸催化剂;以及使用固体路易斯酸催化剂在水溶液中进行化学反应的方法。通过使可以在水溶液中水解以形成氧化物的有机钛化合物与水以及酸或碱催化剂两者反应,可以获得用作路易斯酸的无定形含水氧化钛。该路易斯酸催化剂在包括葡萄糖形成羟甲基糠醛的反应在内的各种反应中显示出优异的效果。

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