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NOVEL SILICON-CONTAINING ALICYCLIC POLYIMIDE RESIN, POLYAMIC ACID RESIN, AND MANUFACTURING METHOD FOR SAME

机译:新型含硅的脂族聚酰亚胺树脂,多聚酸树脂及其制造方法

摘要

A polyimide resin including repeating units represented by formula (1):; embedded image ;wherein R is a diamine residue or a diisocyanate residue; m is an integer of 2 to 30; any of silicon atoms bonded to norbornane rings is in exo configuration with respect to the norbornane rings; and any of imide rings bonded to the norbornane rings is in exo configuration with respect to the norbornane rings, and a polyamic acid resin including repeating units represented by formula (2):; embedded image ;wherein R is a diamine residue; m is an integer of 2 to 30; any of silicon atoms bonded to norbornane rings is in exo configuration with respect to the norbornane rings; and any of amide groups and carboxyl groups bonded to the norbornane rings is in exo configuration with respect to the norbornane rings. The polyimide resin is soluble in general-purpose solvents, has a good transparency and a high molecular weight, and is excellent in mechanical properties, such as tensile strength and elongation.
机译:聚酰亚胺树脂,其包含式(1)所示的重复单元: “嵌入式图像” ;其中R为二胺残基或二异氰酸酯残基; m是2至30的整数;结合降冰片烷环的任何硅原子相对于降冰片烷环为exo构型;结合降冰片烷环的酰亚胺环中的任何一个相对于降冰片烷环为exo构型,聚酰胺酸树脂包括式(2)所示的重复单元: “嵌入式图像” ;其中R是二胺残基; m是2至30的整数;结合降冰片烷环的任何硅原子相对于降冰片烷环为exo构型;并且与降冰片烷环键合的酰胺基和羧基均处于外构型。聚酰亚胺树脂可溶于通用溶剂中,具有良好的透明性和高分子量,并且具有优异的机械性能,例如拉伸强度和伸长率。

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