The invention is directed to an antimicrobial membrane, to a method for preparing said antimicrobial membrane, to a process of operating said antimicrobial membrane, and to uses of said antimicrobial membrane. The antimicrobial membrane of the invention comprises on at least one side of the membrane a multilayer coating, said multilayer coating having alternate polycation and polyanion layers, wherein one or more polycation layers and one or more polyanion layers comprise metal nanoparticles having antimicrobial activity, wherein i) said metal nanoparticles comprise silver; and ii) at least 75 wt.% of said metal is present in a reduced form.
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