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Water-based polyurethane coatings and coatings made from such coatings with high scratch resistance and good chemical resistance

机译:水性聚氨酯涂料和由这种涂料制成的涂料,具有高耐刮擦性和良好的耐化学性

摘要

Disclosed are aqueous coating compositions comprising at least one hydroxyl-containing compound (A), at least one compound (B) having isocyanate groups and also having hydrolyzable silane groups, and at least one catalyst (C) wherein the compound (B) has 10 mol % to less than 90 mol % of at least one structural unit (I) -N(X-SiR''x(OR')3-x)n(X'-SiR''y(OR')3-y)m(I) Where R'=hydrogen, alkyl or cycloalkyl, X, X'=linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms, R''=alkyl, cycloalkyl, aryl or aralkyl, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, and more than 10 to 90 mol % of at least one structural unit (II) -Z-(X-SiR''x(OR')3-x) (II), where Z=-NH-, -NR-, -O- or -S-, where R=alkyl, cycloalkyl, aryl or aralkyl, and x, X, R' and R'' have the definition indicated for formula (I).
机译:公开了一种水性涂料组合物,其包含至少一种含羟基的化合物(A),至少一种具有异氰酸酯基并且还具有可水解硅烷基的化合物(B)和至少一种催化剂(C),其中化合物(B)具有10 (I)-N(X-SiR''x(OR')3-x)n(X'-SiR''y(OR')3-y的摩尔百分比至小于90摩尔% m(I)其中R'=氢,烷基或环烷基,X,X'=具有1至20个碳原子的直链和/或支链亚烷基或亚环烷基,R” =烷基,环烷基,芳基或芳烷基,n = 0〜2,m = 0〜2,m + n = 2,x,y = 0〜2,且至少一种结构单元(II)-Z-(X-SiR′ 'x(OR')3-x)(II),其中Z = -NH-,-NR-,-O-或-S-,其中R =烷基,环烷基,芳基或芳烷基,以及x,X,R '和R''具有式(I)所示的定义。

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