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Trifunctional (meth) acrylate compound and polymerizable composition containing the compound

机译:三官能(甲基)丙烯酸酯化合物和包含该化合物的可聚合组合物

摘要

A trifunctional (meth)acrylate compound of general formula (I) and a polymerizable composition containing the compound. The compounds (I) wherein rings A 1 , A 2 , and A 3 are each benzene or naphthalene, with at least one of them being naphthalene or wherein X 1 , X 2 , and X 3 are each -COO- or -OCO- are preferred. More preferably, ring A 3 is naphthalene. Even more preferably, the compound is alone capable of retaining a liquid crystal phase at or below 30°C. wherein M 1 , M 2 , and M 3 are each methyl, etc.; ring A 1 , A 2 , and A 3 are each benzene, naphthalene, etc.; Z 1 , Z 2 , and Z 3 are each C1-C6 alkyl, etc.; X 1 , X 2 , and X 3 are each -COO-, -OCO-, etc.; Y 1 and Y 2 are each -L 1 -, etc.; Y 3 is -L 2 -, etc.; L 1 and L 2 are each C1-C8 alkylene; a, b, and c are the numbers of the substituents on ring A 1 , A 2 , and A 3 , respectively, each being an integer of (2u+2) or smaller (u is the number of the 6-membered rings composing the substituted monocyclic or fused ring); at least one of a, b, and c is 1 or greater; p is an integer of 1 to 8; q and r are each an integer of 1 to 3; and s and t are each 0 or 1, satisfying (s+t‰¥1).
机译:通式(I)的三官能(甲基)丙烯酸酯化合物和包含该化合物的可聚合组合物。化合物(I),其中环A 1,A 2和A 3分别为苯或萘,其中至少一个为萘或其中X 1,X 2和X 3分别为-COO-或-OCO-是首选。更优选地,环A 3为萘。甚至更优选地,该化合物单独能够在或低于30℃下保持液晶相。其中M 1,M 2和M 3各自为甲基等。环A 1,A 2和A 3分别为苯,萘等。 Z 1,Z 2和Z 3分别为C1-C6烷基等。 X 1,X 2和X 3分别是-COO-,-OCO-等。 Y 1和Y 2分别是-L 1-等。 Y 3是-L 2-,等等。 L 1和L 2各自为碳数1〜8的亚烷基。 a,b和c分别是环A 1,A 2和A 3上的取代基的数目,各自是(2u + 2)或更小的整数(u是组成6元环的数目取代的单环或稠环); a,b和c中的至少一个为1或更大; p是1至8的整数; q和r均为1至3的整数;且s和t分别为0或1,满足(s + t‰¥1)。

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