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Poly(meth)acrylimide having improved optical and color properties, particularly under thermal load

机译:聚(甲基)丙烯酰亚胺具有改善的光学和彩色性能,尤其是在热负荷下

摘要

Process for preparing molding materials MM with improved optical and color properties, consisting of a polymer PM which contains units of the formula I; embedded image in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder,in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for color stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II; embedded image in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups. Shaped bodies obtainable by the process, especially light waveguides, have a low tendency to yellowing under thermal stress, coupled with a low haze, and also a stable and high transparency.
机译:制备具有改善的光学和颜色性能的模制材料MM的方法,该方法由包含式I单元的聚合物PM组成; “嵌入式图像” 其中R 1 和R 2 分别是氢和甲基,而R 3 是氢,C 1 -C 18 -烷基,C 5 -C 8 -环烷基,C 6 -C 10 -芳基,C 6 -C 10 -芳基-C 1 -C 4 -烷基,其中这些基团最多可被选自C 1 -C 4 -烷氧基和卤素的基团三取代,这些基团是通过本身已知的在反应中的酰亚胺化反应制备的挤出机其中,在酰亚胺化反应完成后,将一定量的一种或多种对颜色稳定有效的还原性磷化合物P加入到聚合物PM中,其特征在于,磷化合物是选自以下的有机磷化合物OP:式II化合物; “嵌入式图像” 其中R 4 和R 5 分别独立地是氢或最多被C 1 -五取代的芳族6元环C 4 -烷基和/或C 5 -C 8 -环烷基。通过该方法可获得的成形体,特别是光波导,在热应力下变黄的趋势低,雾度低,并且稳定且透明性高。

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