首页> 外国专利> PLASTICIZER FREE CAULK AND SEALANTS HAVING IMPROVED AGED WET ADHESION

PLASTICIZER FREE CAULK AND SEALANTS HAVING IMPROVED AGED WET ADHESION

机译:改善老化胶水的增塑剂免费填缝剂和密封剂

摘要

The present invention provides filled aqueous caulk and sealant compositions made from high solids aqueous binders chosen from copolymers having a mixture of backbone acid and hydroxyl groups that are copolymerized from 0.5 to 7.5 wt.%, based on total monomer weight, of an hydroxyl group containing monomer, and mixed backbone acid copolymers that are copolymerized from methacrylic acid (MAA) with a second acid monomer having a lower pKa than the pKa of MAA. Preferred, compositions comprise one or more organosilane exhibit the adhesion and joint movement capability required by ASTM C-920-08, as well as good weatherability and aged wet adhesion to glass, even at a filler to binder ratio of 0.2:1 to 4:1.
机译:本发明提供了由高固体含量的水性粘合剂制成的填充的水性填缝剂和密封剂组合物,所述粘合剂选自具有主链酸和羟基的混合物的共聚物,所述主链酸和羟基的混合物基于单体的总重量为0.5-7.5wt。%,含羟基。单体,以及由甲基丙烯酸(MAA)与pKa低于MAA的pKa的第二种酸单体共聚而成的混合骨架酸共聚物。优选的组合物包含一种或多种有机硅烷,即使填料与粘合剂的比例为0.2:1至4:4,也表现出ASTM C-920-08要求的粘合性和接头运动能力,以及良好的耐候性和对玻璃的老化湿粘合性。 1。

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