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BACK PLATE-ELECTRODE-MEMBRANE ASSEMBLY FOR A REDOX, FLOW ENERGY STORAGE ELECTROCHEMICAL CELL

机译:氧化还原,流能存储电化学电池的背板-电极膜组件

摘要

Effects of non homogeneity of elastically compressed carbon felt electrodes (2) in terms of permeability to a forced liquid flow and of excessive passive power requirement for adequately irrigating the porous electrodes (2) with fresh electrolyte solution, without detracting from the ability to ensure a good electrical contact between the felt electrode and a conductive back plate (1) are alleviated by providing a first plurality of spaced parallel sinuous open channels (sc1) that originate from an inlet manifolding flow space (4min) extending along one side of the assembly into which the electrolyte solution enters the cell compartment through one or more inlet ports (4h). The sinuous channels (sc1) terminate short of reaching an outlet manifolding flow space (4mout) extending along the opposite side of the channeled area, from which the electrolyte solution exits the cell compartment through one or more outlet ports. Vice versa, a second plurality of spaced parallel sinuous open channels (sc2), interleaved to the channels (sc1) of the first plurality, originate from the outlet manifolding flow space (4mout) and terminate short of reaching the inlet manifolding flow space (4min). Preferably, through holes (2h) with diameter equal to or larger than the width of the channels (sc1, sc2) of the interleaved sinuous channel-works in the contact area of the conductive back plate (1) and spaced along a sinuous track lines in the carbon felt electrode, coincide with either a underlying electrolyte solution distribution channel (sc1) or with an underlying electrolyte solution drainage channel (sc2), respectively.
机译:弹性压缩碳毡电极(2)的非均质性对强制液体流动的渗透性和过高的被动功率要求(用足够的新鲜电解液充分灌溉多孔电极(2)的能力)的影响,通过提供第一多个间隔开的平行正弦形开口通道(sc1),减轻了毡制电极和导电背板(1)之间的良好电接触,该通道由沿着组件的一侧延伸到其内部的进气歧管流动空间(4min)产生。电解液通过一个或多个入口(4h)进入电池仓。弯曲通道(sc1)终止,直到到达出口歧管流动空间(4mout),该出口歧管流动空间沿着通道区域的相对侧延伸,电解质溶液从该出口歧管流动空间通过一个或多个出口离开电池室。反之亦然,与第一组通道的交错通道(sc1)交错的第二组多个隔开的平行正弦形开放通道(sc2),从出口歧管流动空间(4mout)开始并终止,直到到达入口歧管流动空间(4min )。优选地,直径等于或大于交错的弯曲通道的通道(sc1,sc2)的宽度的通孔(2h)在导电背板(1)的接触区域中并且沿着弯曲轨迹线间隔开。在碳毡电极中,分别与下面的电解质溶液分配通道(sc1)或下面的电解质溶液排放通道(sc2)一致。

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