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Novel reactive polymer catalysts for two-component epoxy resin systems

机译:用于二组分环氧树脂体系的新型反应性聚合物催化剂

摘要

The present invention relates to at least one (hydroxymethyl) phenol of the general formula (I), wherein R1 is hydrogen or —CH3, R2 is —CH2OH and R3 is hydrogen or —CH3. Oligomer condensation products obtainable from one polyamine and optionally at least one phenolic compound having two reactive centers by reaction with the methylol group of (hydroxymethyl) phenol are described. This type of condensation product can be used as a polymerization catalyst for epoxy resins, in which case a faster curing time and corresponding pot life can be achieved with a two-component epoxy resin adhesive. It is therefore possible to further reduce the production time in industrial applications and to develop new application fields in which adhesive bonding can be applied instead of threaded connections. The condensation products described above further have the advantage that no toxic substances such as formaldehyde or dimethylamine need to be used or released in the synthesis of these products when compared to similar conventional condensation products. Have. The invention further relates to a process for producing the above-mentioned oligomeric condensation compounds and their use in curing epoxy resin systems.
机译:本发明涉及至少一种通式(I)的(羟甲基)苯酚,其中R 1是氢或-CH 3,R 2是-CH 2 OH并且R 3是氢或-CH 3。描述了可通过与(羟甲基)苯酚的羟甲基反应从一种多胺和任选地至少一种具有两个反应性中心的酚类化合物获得的低聚物缩合产物。这种类型的缩合产物可用作环氧树脂的聚合催化剂,在这种情况下,使用二组分环氧树脂粘合剂可实现更快的固化时间和相应的适用期。因此,可以进一步减少工业应用中的生产时间,并且可以开发新的应用领域,在该领域中可以采用粘合剂代替螺纹连接。上述缩合产物的优点还在于,与类似的常规缩合产物相比,在这些产物的合成中不需要使用或释放​​有毒物质,例如甲醛或二甲胺。有。本发明进一步涉及制备上述低聚缩合化合物的方法及其在固化环氧树脂体系中的用途。

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