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Stirring reaction tank, stirring reactor, and method for controlling chlorine leaching reaction redox potential

机译:搅拌反应槽,搅拌反应器及氯浸出反应氧化还原电位的控制方法

摘要

PROBLEM TO BE SOLVED: To provide a stirred reaction tank, a stirred reaction device and a method for controlling chlorine leaching reaction oxidation-reduction potential, when nonferrous metal is leached from nonferrous metal sulfide-containing nonferrous metal raw material using a chlorine gas, which can obtain the high leaching rate of a metallic element(s) without causing the reduction in the availability of the chlorine gas and the increase in a sulfur oxidation rate.SOLUTION: Using a stirred reaction tank 50 provided with: a chlorine gas feeding part 30 including a chlorine blowing nozzle 32 in which the position in the tank of a nozzle tip part 32A provided with a chlorine blowing port 31 is freely adjusted from the outside of the tank; and sensors 40A, 40B for measuring oxidation-reduction potential of measuring oxidation-reduction potential at a plurality of positions including the upper part of the tank and the lower part of the tank, a chlorine gas is fed into the tank by the chlorine gas feeding means, whether or not a difference in the oxidation-reduction potential measured values obtained with the sensors lies within a prescribed value is determined by a controller 60, and the control of moving the tip position of the chlorine blowing nozzle in the stirred reaction tank till the difference reaches within the prescribed value is performed.
机译:解决的问题:提供一种搅拌反应槽,搅拌反应装置以及用于在使用氯气从含有色金属硫化物的有色金属原料中浸出有色金属时控制氯的浸出反应氧化还原电位的方法,可以得到金属元素的高浸出率而不会导致氯气的利用率的降低和硫的氧化率的增加。解决方案:使用具有以下装置的搅拌反应槽50:氯气供给部30具备氯吹嘴32,在该氯吹嘴32中,具有氯吹出口31的喷嘴前端部32A在容器内的位置能够从容器外自由地调整。传感器40A,40B用于测量氧化还原电位,该传感器在包括罐的上部和罐的下部的多个位置处测量氧化还原电位,通过氯气进给将氯气输入到罐中即,由控制器60判断由传感器获得的氧化还原电位测量值的差是否在规定值内,并控制搅拌反应槽中的吹氯喷嘴的前端位置移动至差达到规定值以内。

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