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CATHODIZED GOLD NANOPARTCLE GRAPHITE PENCIL ELECTRODE AND METHOD FOR GLUCOSE DETECTION
CATHODIZED GOLD NANOPARTCLE GRAPHITE PENCIL ELECTRODE AND METHOD FOR GLUCOSE DETECTION
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机译:阳离子化金纳米颗粒石墨电极及葡萄糖检测方法
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摘要
The cathodized gold nanoparticle graphite pencil electrode is a sensitive enzymeless electrochemical glucose sensor based on the cathodization of AuNP-GPE. Cyclic voltammetry shows that advantageously, the cathodized AuNP-GPE is able to oxidize glucose partially at low potential (around −0.27 V). Fructose and sucrose cannot be oxidized at 0.1 V, thus the glucose oxidation peak at around −0.27 V is suitable enough for selective detection of glucose in the presence of fructose and sucrose. However, the glucose oxidation peak current at around −0.27 V is much lower which should be enhanced to obtain low detection limit. The AuNP-GPE cathodization increases the oxidation peak current of glucose at around −0.27 V. The dynamic range of the sensor is in the range between 0.05 to 5.0 mM of glucose with good linearity (R2=0.999). Almost no interference effect was observed for sensing of glucose in the presence of fructose, sucrose and NaCl.
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