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Method for isolating palladium from solid materials with developed surface, containing trace amounts of noble metals

机译:从表面发达的,含有痕量贵金属的固体材料中分离钯的方法

摘要

The object of the invention is to extract small quantities of palladium from solid materials with a developed surface, including trace amounts of other precious metals such as platinum and the genus, in particular from used catalysts, and in particular automotive converters. The invention consists of the selective separation of the ion complex palladium by the use of sorbent in the form of a hydrophilic acrylic polymer not containing functional groups, which favours a polymer of methacrylic acid ester or sorbent in the form of a hydrophilic polymer of styrene with divinylbenzene, impregnated with phosphoric acids,favourable bis(2,4,4-trimethylpentyl)phosphine or bis (2,4,4 -trimethylpentyl)dithiophosphine, dissolved in acetone. Isolated by the invention of the palladium complex, it is the starting product for the simple and easy extraction of the palladium itself, and the remaining solution obtained in an unchanged composition serves for the further recovery of the precious metal ions contained therein.
机译:发明内容本发明的目的是从具有发达表面的固体材料中提取少量钯,所述钯包括痕量的其他贵金属,例如铂和属,特别是从用过的催化剂,尤其是汽车转化器中。本发明包括通过使用不包含官能团的亲水性丙烯酸聚合物形式的吸附剂选择性分离离子配合物钯,这有利于甲基丙烯酸酯的聚合物或苯乙烯的亲水性聚合物形式的吸附剂与溶于磷酸的磷酸二乙烯苯,有利的双(2,4,4-三甲基戊基)膦或双(2,4,4-三甲基戊基)二硫代膦溶解在丙酮中。通过本发明的钯络合物的分离,它是用于简单和容易地提取钯本身的起始产物,并且以不变的组成获得的剩余溶液用于进一步回收其中所含的贵金属离子。

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