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HIGHLY DISPERSED TRANSITION METAL CATALYST AND HIGH DISPERSION SUPPORTING METHOD OF TRANSITION METAL ATOMS ON SURFACE OF SILICA SUPPORT
HIGHLY DISPERSED TRANSITION METAL CATALYST AND HIGH DISPERSION SUPPORTING METHOD OF TRANSITION METAL ATOMS ON SURFACE OF SILICA SUPPORT
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机译:高分散过渡金属催化剂及二氧化硅支撑表面上过渡金属原子的高分散支撑方法
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摘要
PROBLEM TO BE SOLVED: To provide a highly dispersed transition metal catalyst comprising transition metal atoms dispersed in an atomic level on a support surface, and to provide a high dispersion supporting method of transition metal atoms on the surface of a silica support.SOLUTION: The highly dispersed transition metal catalyst is obtained by: forming a transition metal-ammonium coordination complex ion in a mixed liquid obtained by adding an inorganic salt of a transition metal in an aqueous ammonium solution; contacting the mixed liquid with a silica support to bind the transition metal to oxygen atoms of silanol groups on a surface of the silica support; chemically bonding the transition metal, the oxygen, and silicon atoms on a surface of the silica support; recovering the silica support; and having the transition metal atom high dispersion supported in an atomic level on an exposed surface of the silica support.
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