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MONOLITHIC STRUCTURED CATALYST FOR CARBON MONOXIDE GASE-PHASE COUPLING TO DIALKYL OXALATE amp; PREPARATION METHOD AND APPLICATION THEREOF
MONOLITHIC STRUCTURED CATALYST FOR CARBON MONOXIDE GASE-PHASE COUPLING TO DIALKYL OXALATE amp; PREPARATION METHOD AND APPLICATION THEREOF
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机译:一氧化碳气相色谱与草酸二烷基酯的单分子结构催化剂及其制备方法和应用
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摘要
Provided was a monolithic catalyst for synthesizing an oxalate by carbon monoxide (CO) gaseous-phase coupling, a preparation method and the use thereof. In the catalyst, a ceramic honeycomb or a metal honeycomb was used as skeletal carrier, metal oxides were used as a carrier coating, precious metals Pt, Pd, Ir, Rh were used as active ingredients, as well as Fe, Co, Ni were used as additives, wherein the carrier coating accounts for 5 to 50 wt. % of the honeycomb carrier; the active ingredients of the catalyst account for 0.1 to 5 wt. % of the carrier coating; the additives of the catalyst account for 0.3 to 10 wt. % of the carrier coating; and the atomic ratio of the active ingredients to the additives was 0.1 to 3. the reaction for synthesizing the oxalate was carried out in a fixed bed reactor, wherein, N2 was used as a carrier gas. The volume ratio of N2:CO:Alkyl nitrite was 20-80:5-60:10-40, and the retention time was 0.5-10 s.
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机译:提供一种通过一氧化碳(CO)气相偶联合成草酸酯的整体式催化剂,其制备方法及其用途。在催化剂中,使用陶瓷蜂窝或金属蜂窝作为骨架载体,使用金属氧化物作为载体涂层,使用贵金属Pt,Pd,Ir,Rh作为活性成分,并使用Fe,Co,Ni作为载体。用作添加剂,其中载体涂料占5至50 wt。蜂窝载体的百分比;催化剂的活性成分占0.1至5重量%。载体涂层的百分比;催化剂的添加剂占0.3至10重量%。载体涂层的百分比;活性成分与添加剂的原子比为0.1〜3。草酸盐的合成反应在固定床反应器中进行,其中N 2被用作载气。 N 2:CO:亚硝酸烷基酯的体积比为20-80:5-60:10-40,保留时间为0.5-10s。
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