M(LL1)m1(LL2)m2(X)m3·CI Formula (1)wherein M represents a metal atom, LL1, LL2, and X each are a ligand, CI represents a counter ion, m1 represents an integer of 1 to 3, m2 and m3 each represent an integer of 0 to 2."/>
Method of producing photoelectric conversion element, photoelectric conversion element and photoelectrochemical cell
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Method of producing photoelectric conversion element, photoelectric conversion element and photoelectrochemical cell
Method of producing photoelectric conversion element, photoelectric conversion element and photoelectrochemical cell
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机译:光电转换元件的制造方法,光电转换元件和光电化学电池
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摘要
A method of producing a photoelectric conversion element, which contains an electrically conductive support, a photosensitive layer having porous semiconductor fine particles that have adsorbed a dye formed on the support, a charge transfer layer; and a counter electrode; containing the steps of: applying a dispersion liquid, in which the content of solids excluding semiconductor fine particles is 1% by mass or less based on the total amount of the dispersion liquid, on the support, to form a coating; heating the coating, to obtain porous semiconductor fine particles; and sensitizing the porous semiconductor fine particles by a dye having a structure represented by Formula (1):M(LL1)m1(LL2)m2(X)m3·CI Formula (1)wherein M represents a metal atom, LL1, LL2, and X each are a ligand, CI represents a counter ion, m1 represents an integer of 1 to 3, m2 and m3 each represent an integer of 0 to 2.
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机译:1。一种光电转换元件的制造方法,其包含导电性支撑体,具有吸附在该支撑体上的染料的多孔半导体微粒的光敏层,电荷转移层;和对电极。所述方法包括以下步骤:在所述载体上涂布分散液,以所述分散液为基体,其中,所述分散液中,除所述半导体微粒以外的固体成分相对于所述分散液的总量为1质量%以下。加热涂层,以获得多孔半导体细颗粒。并通过具有式(1)表示的结构的染料使多孔半导体微粒敏化:<?in-line-formulae description =“在线公式” end =“ lead”?> M I>( LL I> 1 Sup>) m I> 1 Sub>( LL I> 2 Sup>) m I> 2 Sub>(< I> X I>) m I> 3 Sub>·CI公式(1)<?in-line-formulae description =“ In-line Formulae” end =“ tail” ?>其中M代表金属原子,LL 1 Sup>,LL 2 Sup>,X分别为配体,CI代表抗衡离子,m 1 Sub>代表整数1到3,m 2 Sub>和m 3 Sub>分别表示0到2的整数。
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