首页> 外国专利> METHOD FOR MANUFACTURING POLYACRYLONITRILE-BASED PRECURSOR FIBER FOR CARBON FIBER, AND POLYACRYLONITRILE-BASED PRECURSOR FIBER MANUFACTURED THEREBY

METHOD FOR MANUFACTURING POLYACRYLONITRILE-BASED PRECURSOR FIBER FOR CARBON FIBER, AND POLYACRYLONITRILE-BASED PRECURSOR FIBER MANUFACTURED THEREBY

机译:制造用于碳纤维的基于聚丙烯腈的前体纤维的方法,以及由此制备的基于聚丙烯腈的前体纤维

摘要

The present invention relates to a method for manufacturing polyacrylonitrile-based precursor fiber for carbon fiber. When manufacturing an acrylonitrile-based copolymer into polyacrylonitrile-based precursor fiber for carbon fiber by passing acrylonitrile-based filament through the processes of washing with water, hot water stretching, primary drying, hot-steam stretching, secondary drying and winding, secondarily dried polyacrylonitrile-based filament is irradiated. The polyacrylonitrile-based precursor fiber for carbon fiber manufactured by the method of the present invention has a specific gravity of 1.2-1.4 and is thermally stabilized as the cyclization reaction is conducted in a portion of pyridine in the molecular structure by the irradiation. As a result, the polyacrylonitrile-based precursor fiber for carbon fiber manufactured according to the present invention can shorten the heat stabilization treatment time for the manufacture of carbon fiber, and can perform the oxidation process for the manufacture of carbon fiber only for a short period of time at a relatively lower temperature compared to the past due to a decreased heating value in the oxidation process, thereby simplifying the manufacture process of carbon fiber and enhancing the productivity.;COPYRIGHT KIPO 2016
机译:碳纤维用聚丙烯腈类前体纤维的制造方法技术领域本发明涉及碳纤维用聚丙烯腈类前体纤维的制造方法。通过使丙烯腈基长丝经过水洗,热水拉伸,一次干燥,热蒸汽拉伸,二次干燥和卷绕,二次干燥的聚丙烯腈等工序,将丙烯腈基共聚物制成碳纤维用聚丙烯腈基前体纤维时基细丝被照射。通过本发明的方法制造的用于碳纤维的基于聚丙烯腈的前体纤维具有1.2-1.4的比重,并且由于通过辐射在分子结构中的一部分吡啶中进行环化反应而被热稳定。结果,根据本发明制造的用于碳纤维的聚丙烯腈基前体纤维可以缩短用于制造碳纤维的热稳定化处理时间,并且可以仅在短时间内进行用于制造碳纤维的氧化过程。由于氧化过程中的发热量降低,因此与以前相比,温度处于相对较低的水平,从而简化了碳纤维的制造过程并提高了生产率。; COPYRIGHT KIPO 2016

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