首页> 外国专利> PROCESS FOR PRODUCING ACRYLIC ACID, AND PROCESS FOR PRODUCING HYDROPHILIC RESIN AND PROCESS FOR PRODUCING WATER ABSORPTIVE RESIN USING THE PROCESS

PROCESS FOR PRODUCING ACRYLIC ACID, AND PROCESS FOR PRODUCING HYDROPHILIC RESIN AND PROCESS FOR PRODUCING WATER ABSORPTIVE RESIN USING THE PROCESS

机译:丙烯酸的制备方法,亲水性树脂的制备方法以及使用该方法制备吸水性树脂的方法

摘要

[Problem];There is provided, in a process for producing acrylic acid having a catalytic gas-phase oxidation reaction step, a condensation step, a collection step, a distillation step, a crystallization step, an acrylic acid recovering step or the like, a production method for acrylic acid, in which contamination of acrylic acid with protoanemonin without providing any additional purification treatment to the resultant purified acrylic acid can be reduced.;[Solution];The problems described above can be solved by providing the production method for acrylic acid comprising A) a step obtaining an acrylic acid-containing gas by a catalytic gas-phase oxidation reaction of gas containing a acrylic acid raw material; B) a step of obtaining the acrylic acid-containing solution by introducing the acrylic acid-containing gas to the collection column or the condensation column and performing collection or condensation; C) a step of obtaining the crude acrylic acid by introducing the acrylic acid-containing solution to the distillation column or the crystallizer and performing distillation or crystallization, wherein a step of heat treating the acrylic acid-containing solution or the crude acrylic acid containing 100 ppm by mass or more of protoanemonin, under the condition of 100°C or more of temperature, 1 hour or more of time and a step of introducing the heat-treated acrylic acid-containing solution or the crude acrylic acid to the collection column, the condensation column, the distillation column or the crystallizer, are included.
机译:[问题]在具有催化气相氧化反应步骤,缩合步骤,收集步骤,蒸馏步骤,结晶步骤,丙烯酸回收步骤等的丙烯酸的制备方法中,提供了一种一种丙烯酸的生产方法,其中可以减少对丙烯酰胺的污染而无需对所得纯化的丙烯酸进行任何额外的纯化处理。[解决方案];可以通过提供一种丙烯酸的生产方法来解决上述问题。酸包括A)通过含丙烯酸原料的气体的催化气相氧化反应获得含丙烯酸的气体的步骤; B)通过将含丙烯酸的气体引入到收集塔或冷凝塔中并进行收集或冷凝来获得含丙烯酸的溶液的步骤; C)通过将含丙烯酸的溶液引入蒸馏塔或结晶器中并进行蒸馏或结晶而获得粗丙烯酸的步骤,其中热处理含丙烯酸的溶液或含100的粗丙烯酸的步骤在100℃以上的温度,1小时以上的时间的条件下,将经热处理的含丙烯酸溶液或粗丙烯酸导入到收集塔中的步骤中,原Promonanemonin的质量ppm以上。包括冷凝塔,蒸馏塔或结晶器。

著录项

  • 公开/公告号EP2275400B1

    专利类型

  • 公开/公告日2017-01-11

    原文格式PDF

  • 申请/专利权人 NIPPON CATALYTIC CHEM IND;

    申请/专利号EP20090738750

  • 发明设计人 ISHIKAWA MASARU;SAKAMOTO KAZUHIKO;

    申请日2009-04-24

  • 分类号C07C51/25;C07C51/43;C07C51/44;C07C51/487;C07C57/04;C08F220/06;

  • 国家 EP

  • 入库时间 2022-08-21 14:06:36

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