首页> 外国专利> CRYSTAL GROWTH CONTROL AGENT, METHOD FOR FORMING p-TYPE SEMICONDUCTOR MICROPARTICLES OR p-TYPE SEMICONDUCTOR MICROPARTICLE FILM, COMPOSITION FOR FORMING HOLE TRANSPORT LAYER, AND SOLAR CELL

CRYSTAL GROWTH CONTROL AGENT, METHOD FOR FORMING p-TYPE SEMICONDUCTOR MICROPARTICLES OR p-TYPE SEMICONDUCTOR MICROPARTICLE FILM, COMPOSITION FOR FORMING HOLE TRANSPORT LAYER, AND SOLAR CELL

机译:晶体生长控制剂,p型半导体微粒或p型半导体微粒膜的形成方法,形成空穴传输层的组成以及太阳能电池

摘要

First, there is provided a crystal growth control agent which is capable of suppressing an increase in a crystal size of a p-type semiconductor, and performing chemical modification on a surface of p-type semiconductor microparticle, a method for forming p-type semiconductor microparticles or a p-type semiconductor microparticle film by using the crystal growth control agent, a composition for forming a hole transport layer of a solar cell, and a solar cell using the composition for forming a hole transport layer. Second, there is provided a composition for forming a hole transport layer which is capable of prompting crystallization and fine pulverization of the p-type semiconductor and performing the chemical modification on the surface of the p-type semiconductor microparticle even in the case where an organic salt (an ionic liquid) containing an anion other than the thiocyanate ion is used, and a solar cell using the composition for forming a hole transport layer. According to the present invention, the crystal growth control agent contains at least one of sulfur-containing compounds (except for thiocyanate) selected from the group consisting of a compound, which generates a thiolate anion due to dissociation of a proton or a cation, and a disulfide compound, and controls crystal growth of a p-type semiconductor.
机译:首先,提供一种晶体生长控制剂,形成p型半导体的方法,该晶体生长控制剂能够抑制p型半导体的晶体尺寸的增加并且能够在p型半导体微粒的表面上进行化学改性。通过使用晶体生长控制剂的微粒或p型半导体微粒膜,用于形成太阳能电池的空穴传输层的组合物,以及使用该太阳能电池的用于形成空穴传输层的组合物。第二,提供了一种用于形成空穴传输层的组合物,即使在有机物的情况下,该组合物也能够促进p型半导体的结晶和精细粉碎并且能够在p型半导体微粒的表面上进行化学改性。使用含有除硫氰酸根离子以外的阴离子的盐(离子液体),以及使用了用于形成空穴传输层的组合物的太阳能电池。根据本发明,晶体生长控制剂包含选自以下的至少一种含硫化合物(硫氰酸盐除外):该化合物由于质子或阳离子的离解而产生硫醇根阴离子,和二硫化物化合物,并控制p型半导体的晶体生长。

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