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Method for complex utilization of phosphogypsum

机译:磷石膏的综合利用方法

摘要

The method of total phospholipid elimination consists of the fractionation of phospholipids, followed by the rinsing of them with a sulphuric acid solution of 2-15% concentration and mixing at a temperature of 50-80-C, after which the resulting mixture is separated into a liquid fraction and a residue mainly containing calcium sulphate. The method is characterised by the precipitation from the liquid fraction of metals, mainly lanthanes, phosphates and sulphates of soluble metals in diluted sulphuric acid, and the residue containing mostly calcium sulphates is converted into ammonia water and carbon dioxide into ammonium sulphate and calcium carbonate,after which the filtered and dried calcium sediment in the form of carbonate is dissolved in a solution of nitric acid with a concentration of 15-30% constantly stirring and then produced during the reaction CO2 is reversed and used in the conversion process of the first phase of sediment, and the resulting mixture is separated into a solution of calcium nitrate with dissolved metals and into a fluoride and silicate deposit with embedded metals.
机译:完全消除磷脂的方法包括分馏磷脂,然后用浓度为2-15%的硫酸溶液冲洗磷脂,并在50-80-C的温度下混合,然后将所得混合物分离为液体馏分和主要含有硫酸钙的残渣。该方法的特点是在稀硫酸中从液态金属(主要是镧系金属,磷酸盐和可溶性金属硫酸盐)的液体级分中沉淀出来,将主要包含硫酸钙的残留物转化为氨水,将二氧化碳转化为硫酸铵和碳酸钙,然后将经过过滤和干燥的碳酸盐形式的钙沉淀物溶解在浓度为15%至30%的硝酸溶液中,不断搅拌,然后在反应过程中产生。将二氧化碳反转并用于第一阶段的转化过程中沉淀,然后将所得混合物分离为硝酸钙与溶解金属的溶液,以及氟化物和硅酸盐与嵌入金属的沉积物。

著录项

  • 公开/公告号PL412427A1

    专利类型

  • 公开/公告日2016-11-21

    原文格式PDF

  • 申请/专利权人 MERKA WŁODZIMIERZ;

    申请/专利号PL20150412427

  • 发明设计人 WŁODZIMIERZ MERKA;

    申请日2015-05-20

  • 分类号C01B25/36;C01B25/22;C01B25/232;C01B25/234;C22B3/08;C22B59;

  • 国家 PL

  • 入库时间 2022-08-21 13:36:56

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