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MOLECULAR SIEVE MODIFICATION METHOD AND CATALYTIC CRACKING CATALYST CONTAINING MOLECULAR SIEVE

机译:分子筛的改性方法及含分子筛的催化裂化催化剂

摘要

The invention relates to a molecular sieve modification method and a catalytic cracking catalyst containing a molecular sieve. The method comprises: mixing a solution containing an ion of a Group IIIB metal in the periodic table, an organic complexing agent, and/or a dispersant and a precipitation agent, and stirring the same to form a suspension containing a precipitant of a Group IIIB element; and mixing the resulting precipitant and a molecular sieve slurry, stirring the same to obtain a mixed slurry containing the precipitant of the Group IIIB element and a molecular sieve, and performing spray drying and optional calcination, to obtain a modified molecular sieve. The catalyst comprises, as calculated based on the catalyst mass being 100%, 10-55% of a modified molecular sieve (on a dry basis), 10-80% of clay (on a dry basis), 0-40% of an inorganic oxide (on an oxide basis), and 5-40% of a binding agent (on an oxide basis). The catalyst has good activity stability and heavy metal contamination resistance.
机译:本发明涉及分子筛的改性方法和含有该分子筛的催化裂化催化剂。该方法包括:将包含元素周期表中的IIIB族金属离子的溶液,有机络合剂和/或分散剂和沉淀剂混合,并将其搅拌以形成包含IIIB族沉淀剂的悬浮液。元件;将得到的沉淀剂和分子筛浆液混合,搅拌,得到含有IIIB族元素的沉淀剂和分子筛的混合浆液,进行喷雾干燥和任选的煅烧,从而得到改性分子筛。基于催化剂质量为100%计算,催化剂包含10-55%的改性分子筛(以干基计),10-80%的粘土(以干基计),0-40%的粘土。无机氧化物(基于氧化物)和5-40%的粘合剂(基于氧化物)。该催化剂具有良好的活性稳定性和抗重金属污染性。

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