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Method for modifying molecular sieve and a catalytic cracking catalyst containing the molecular sieve

机译:修饰分子筛的方法和含有分子筛的催化裂化催化剂

摘要

The invention relates to a molecular sieve modification method and a catalytic cracking catalyst containing a molecular sieve. The method comprises: mixing a solution containing an ion of a Group MB metal in the periodic table, an organic complexing agent, and/or a dispersant and a precipitation agent, and stirring the same to form a suspension containing a precipitant of a Group IIIB element; and mixing the resulting precipitant and a molecular sieve slurry, stirring the same to obtain a mixed slurry containing the precipitant of the Group MB element and a molecular sieve, and performing spray drying and optional calcination, to obtain a modified molecular sieve. The catalyst comprises, as calculated based on the catalyst mass being 100%, 10-55% of a modified molecular sieve (on a dry basis), 10-80% of clay (on a dry basis), 0-40% of an inorganic oxide (on an oxide basis), and 5-40% of a binding agent (on an oxide basis). The catalyst has good activity stability and heavy metal contamination resistance.
机译:本发明涉及一种分子筛改性方法和含有分子筛的催化裂化催化剂。该方法包括:将含有载体Mb金属的离子的溶液混合在周期性表,有机络合剂和/或分散剂和沉淀剂中,并搅拌相同的溶液以形成含有IIIB族沉淀剂的悬浮液元素;并将所得沉淀剂和分子筛浆料混合,搅拌相同的是获得含有Mb元素和分子筛的沉淀剂的混合浆料,并进行喷雾干燥和任选的煅烧,得到改性的分子筛。催化剂包括基于催化剂质量计算的100%,10-55%的改性分子筛(干基),10-80%的粘土(干基),0-40%无机氧化物(氧化物基础),5-40%的粘合剂(氧化物基)。催化剂具有良好的活性稳定性和重金属污染抗性。

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