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GAS BARRIER PACKAGING MATERIAL PRECURSOR, METHOD FOR PRODUCING SAME, GAS BARRIER PACKAGING MATERIAL, AND METHOD FOR PRODUCING PACKAGE
GAS BARRIER PACKAGING MATERIAL PRECURSOR, METHOD FOR PRODUCING SAME, GAS BARRIER PACKAGING MATERIAL, AND METHOD FOR PRODUCING PACKAGE
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机译:气体阻隔包装材料的前体,其制造方法,气体阻隔包装材料和包装的方法
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摘要
This gas barrier packaging material precursor is provided with: a support; a gas barrier layer disposed directly on the support and containing a polycarboxylic acid polymer and at least one silicon compound selected from the group consisting of hydrolyzable silane compounds, hydrolyzates thereof, and their condensates; and a protective layer disposed directly on the gas barrier layer and containing a multivalent metal component, a polyester resin, and a dispersing agent. The water vapor transmission rate of the support at 40°C and a relative humidity of 90% is at least 100 g/m2, the content of the multivalent metal component is 40 to 90 mass% with reference to the total mass of the protective layer, the content of the dispersing agent is 2 to 20 mass% with reference to the multivalent metal component, and the content of the silicon compound is 2 to 25 mass% with reference to the polycarboxylic acid polymer. In measurement of the infrared absorption spectrum of the gas barrier layer, the ratio (α/β) between the maximum peak height (α) for the absorbance in the wavenumber range of 1490 cm–1 to 1659 cm–1 and the maximum peak height (β) for the absorbance in the wavenumber range of 1660 cm–1 to 1750 cm–1 is at least 1 and less than 7.
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机译:该阻气包装材料前体具有:支撑体;气体阻隔层直接设置在载体上,并含有聚羧酸聚合物和至少一种选自可水解硅烷化合物,其水解产物及其缩合物的硅化合物;保护层直接设置在阻气层上,并包含多价金属成分,聚酯树脂和分散剂。载体在40℃和90%相对湿度下的水蒸气透过率至少为100 g / m 2 Sup>,多价金属成分的含量为40-90质量%相对于多价金属成分,相对于保护层的总质量,分散剂的含量为2〜20质量%,相对于多元羧酸聚合物,硅化合物的含量为2〜25质量%。在测量阻气层的红外吸收光谱时,波数范围为1490 cm -1 Sup>至1659 cm的吸光度的最大峰值高度(α)之比(α/β) –1 Sup>和最大吸收峰高度(β)在1660 cm –1 Sup>至1750 cm –1 Sup>的波数范围内至少1且小于7。
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