The present invention relates to a non-cyanide copper-tin alloy electroplating solution, which comprises (A) a copper salt supplying a copper ion and a tin salt supplying a tin ion, (B) a conductive salt, (C) a tetrahydroxypropyl a second complexing agent using 50-70 g / L of ethylenediamine and a second complexing agent using 5-15 g / L of 2,2 ', 2'-nitrilotriethanol Tris (2-hydroxyethyl) amine, (D) And a composition of a brightener. According to the present invention, 1-2 g / L of 1,2-dihydroxybenzene is used as the antioxidant and 1-2 ml / L of 1-formylnaphthalene is used as a polishing agent. Accordingly, the present invention can provide a plating solution which does not contain any nickel and does not cause allergic reaction due to human contact due to the substitution of copper alloy material and other metallic nickel plating, A copper-tin alloy plating liquid having a uniform alloy composition even in long-term use in continuous plating operation can be obtained, and a copper-tin alloy exhibiting a nickel-chromatic appearance at the time of mass production can be obtained, and stable quality and productivity can be obtained There is an effect that can be realized.
展开▼
机译:非氰化物铜锡合金电镀液技术领域本发明涉及一种非氰化物铜锡合金电镀液,其包含(A)提供铜离子的铜盐和提供锡离子的锡盐,(B)导电盐,(C)四羟丙基a使用50-70 g / L的乙二胺的第二种络合剂和使用5-15 g / L的2,2',2'-硝基三乙醇三(2-羟乙基)胺的第二种络合剂,(D)增白剂。根据本发明,使用1-2g / L的1,2-二羟基苯作为抗氧化剂,并且使用1-2ml / L的1-甲酰基萘作为抛光剂。因此,根据本发明,可以提供不含有镍并且不因铜合金材料及其他金属镍镀层的置换而与人接触而引起过敏反应的镀液。即使在长期连续电镀操作中使用,也可以获得合金组成,并且可以获得在批量生产时表现出镍色外观的铜-锡合金,并且可以获得稳定的质量和生产率。可以实现的。
展开▼