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THERMOPLASTIC MOULDING MATERIALS BASED ON ACRYLONITRILE, STYRENE AND BUTADIENE

机译:基于丙烯腈,苯乙烯和丁二烯的热塑成型材料

摘要

The invention relates to thermoplastic moulding materials based on acrylonitrile-butadiene-styrene, comprising a SAN-polymer matrix and a graft copolymer, structured from an agglomerated butadiene rubber-graft base and a SAN-graft envelope. The agglomerated graft base has a bimodal particle size distribution of a fraction x) of non-agglomerated particles having a d50-value in the range from 80 to 120 nm and a fraction y) of agglomerated particles having a d50-value in the range from 350 to 550 nm and a polydispersity U of less than 0.28. The invention further relates to a method for producing the graft copolymer, wherein an acrylate copolymer having a polydispersity U of less than 0.27 and a d50-value of 100 to 150 nm is used for agglomeration. The invention further relates to the use of thermoplastic moulding materials for producing moulded parts.
机译:本发明涉及基于丙烯腈-丁二烯-苯乙烯的热塑性模塑材料,其包含SAN-聚合物基质和接枝共聚物,其由附聚的丁二烯橡胶-接枝基体和SAN-接枝封套构成。附聚的接枝基体的双峰粒度分布是,d50值在80至120 nm范围内的非附聚颗粒的分数x)和d50值在80-120 nm范围内的附聚颗粒的分数y) 350至550 nm,多分散度U小于0.28。本发明还涉及一种制备接枝共聚物的方法,其中将具有小于0.27的多分散度U和100至150nm的d50值的丙烯酸酯共聚物附聚。本发明还涉及热塑性模塑材料在生产模塑部件中的用途。

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