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TYRE FOR A VEHICLE CARRYING HEAVY LOADS, COMPRISING A NEW TREAD

机译:载重轮胎的轮胎,包括新的胎面

摘要

A tyre for a vehicle carrying heavy loads, and comprising a tread having at least a rubber composition containing at least one elastomeric matrix comprising, as a major component, a styrene and butadiene copolymer with a glass transition temperature Tg strictly higher than -65°C and not exceeding -30°C; a reinforcing filler comprising silica as a major component; a chemical cross-linking system; a coupling agent for coupling the elastomeric matrix and the reinforcing filler; a plasticiser system comprising 2 to 15 phr of at least one plasticiser resin having a glass transition temperature Tg of at least 20°C, the total proportion of the plasticiser system in the composition ranging from 2 to 17 phr; and a modifier agent for modifying the styrene and butadiene copolymer, optionally already grafted onto said copolymer, which modifier agent is a 1,3-dipolar compound of general formula (I): A-E-D (I). The symbol D is a functional group comprising at least one nitrogen atom and capable of binding to the copolymer via a [3 +2]-type cycloaddition on a carbon-carbon double bond of the chain of said copolymer; the symbol E is a divalent spacer group linking group D to group A; A is a functional group selected from C1-C20 alkyls, C7-C18 alkylaryls, C7-C18 arylalkyls, optionally substituted, 5 to 6 atom nitrogen heterocycles, optionally substituted, 5 to 6 atom sulfur heterocycles, ester groups, phosphate groups, dialkylamino groups and associative groups comprising at least one nitrogen atom.
机译:用于载重车辆的轮胎,其包括胎面,所述胎面具有至少橡胶组合物,所述橡胶组合物包含至少一种弹性体基体,所述弹性体基体以玻璃化转变温度Tg严格高于-65℃的苯乙烯和丁二烯共聚物作为主要成分。不超过-30°C;以二氧化硅为主要成分的补强填料。化学交联系统;用于偶联弹性体基质和增强填料的偶联剂;增塑剂体系,其包含2至15phr的至少一种玻璃化转变温度Tg为至少20℃的增塑剂树脂,所述增塑剂体系在组合物中的总比例为2至17phr;任选地已经接枝到所述共聚物上的用于改性苯乙烯和丁二烯共聚物的改性剂,该改性剂是通式(I):A-E-D(I)的1,3-偶极化合物。符号D是包含至少一个氮原子并且能够通过在所述共聚物的链的碳-碳双键上的[3 + 2]型环加成而与共聚物结合的官能团;符号E是使基团D与基团A连接的二价间隔基。 A是选自C 1 -C 20烷基,C 7 -C 18烷基芳基,C 7 -C 18芳基烷基,任选取代的5至6个原子氮杂环,任选取代的5至6个原子硫杂环,酯基,磷酸基,二烷基氨基的官能团。包括至少一个氮原子的缔合基团。

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