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Photocurable resin composition for stereolithography production, three-dimensional article produced using the composition, and related production method

机译:用于立体平版印刷生产的光固化树脂组合物,使用该组合物生产的三维制品以及相关的生产方法

摘要

The present invention is (i) at least one radically polymerizable compound (A) represented by the following general formula (I), wherein R1 is a straight chain or branched chain having an average molecular weight of 200 to 3,000 g / mol. A polytetramethylene glycol residue, R2 is a diisocyanate compound residue, R3 is the same or different diisocyanate compound residue from R2, and R4 is AcrO-CH2-CH2-; (AcrO- (AcrO-CH2) 3C-CH2-; AcrO-CH2-CHCH3-, AcrO-CH2-CHC2H5- and (AcrO-CH2) 2C (C2H5) CH2-, and , Acr is CH2 = C (R) -CO-, and R is a hydrogen atom or a methyl group and at least one radical polymerizable compound (A) (Ii) at least one radical polymerizable organic compound (B) different from compound (A), and (iii) a photosensitive radical polymerization initiator (C), wherein the content of the radical polymerizable compound (A) is It is related with the liquid photocurable resin composition for optical shaping | molding which is 5-70 weight% on the basis of the total amount of a compound (A) and (B). The present invention further describes related stereolithographic uses and methods, and the three-dimensional articles produced thereby. [Selection figure] None
机译:本发明是(i)至少一种由以下通式(I)表示的自由基聚合性化合物(A),其中R1是平均分子量为200至3,000g / mol的直链或支链。聚丁二醇残基,R2为二异氰酸酯化合物残基,R3为与R2相同或不同的二异氰酸酯化合物残基,R4为AcrO-CH2-CH2-; (AcrO-(AcrO-CH2)3C-CH2-; AcrO-CH2-CHCH3-,AcrO-CH2-CHC2H5-和(AcrO-CH2)2C(C2H5)CH2-,并且,Acr是CH2 = C(R)- CO-,并且R是氢原子或甲基和至少一种自由基聚合性化合物(A)(Ii)至少一种不同于化合物(A)的自由基聚合性有机化合物(B),和(iii)光敏自由基自由基聚合性化合物(A)的含量为100质量%以下的聚合引发剂(C),相对于光学成形|成型用液体光固化性树脂组合物为5〜70重量%,以化合物( A)和(B)。本发明进一步描述了相关的立体光刻用途和方法,以及由此产生的三维制品。

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