首页> 外国专利> PHOTOCURABLE RESIN COMPOSITION FOR STEREOLITHOGRAPHY PRODUCTION, THREE-DIMENSIONAL ARTICLES OBTAINED WITH SAID COMPOSITION, AND A CORRESPONDING PRODUCTION METHOD

PHOTOCURABLE RESIN COMPOSITION FOR STEREOLITHOGRAPHY PRODUCTION, THREE-DIMENSIONAL ARTICLES OBTAINED WITH SAID COMPOSITION, AND A CORRESPONDING PRODUCTION METHOD

机译:用于立体照相术生产的光固化树脂组合物,具有所述组合物的三维制品以及相应的生产方法

摘要

FIELD: manufacturing technology.;SUBSTANCE: invention relates to a method for stereolithography production. Liquid photocurable resin composition for stereolithography contains (i) at least one radically polymerisable compound (A), represented by the following general formula (I): R4O-CO-NH-R2-NH-CO-O-R1-O-CO-NH-R3-NH-CO-OR4 (I), where R1 is a residue of linear or branched polytetramethylene glycol with average molecular weight from 200 to 3,000 g/mol; R2 is a residue of a diisocyanate compound; R3 is a residue of a diisocyanate compound, same as or different from R2; and R4 selected from AcrO-CH2-CH2-; (AcrO-CH2)2CH-; (AcrO-CH2)3C-CH2-; AcrO-CH2-CHCH3-; AcrO-CH2-CHC2H5- and (AcrO-CH2)2C(C2H5)CH2-, preferably AcrO-CH2-CH2 and more preferably AcrO-CH2-CH2-; where Acr is CH2=C(R)-CO- and R is a hydrogen atom or a methyl group; (ii) at least one radically polymerisable organic compound (B) other than compound (A); and (iii) a photosensitive radical polymerisation initiator (C), wherein the content of the radically polymerisable compound (A) varies from 5 to 70 wt% of the total amount of the compounds (A) and (B). Invention further describes the corresponding stereolithography application and method, as well as three-dimensional articles obtained using said invention.;EFFECT: invention enables to obtain transparent three-dimensional articles which have a lower surface roughness.;10 cl, 6 ex, 1 tbl
机译:立体光刻的制造方法技术领域本发明涉及立体光刻的制造方法。用于立体光刻的液体光固化树脂组合物包含(i)至少一种可自由基聚合的化合物(A),由以下通式(I)表示:R 4 O-CO-NH-R 2 -NH-CO-OR 1 -O-CO-NH-R 3 -NH-CO-OR 4 (I ),其中R 1 是直链或支链聚丁二醇的残基,平均分子量为200至3,000 g / mol; R 2 是二异氰酸酯化合物的残基; R 3 是二异氰酸酯化合物的残基,与R 2 相同或不同。和R 4 选自AcrO-CH 2 -CH 2 -; (AcrO-CH 2 2 CH-; (AcrO-CH 2 3 C-CH 2 -; AcrO-CH 2 -CHCH 3 -; AcrO-CH 2 -CHC 2 H 5 -和(AcrO-CH 2 2 < / Sub> C(C 2 H 5 )CH 2 -,最好是AcrO-CH 2 -CH < Sub> 2 ,更优选AcrO-CH 2 -CH 2 -;其中Acr为CH 2 = C(R)-CO-,R为氢原子或甲基; (ii)除化合物(A)以外的至少一种可自由基聚合的有机化合物(B); (iii)光敏性自由基聚合引发剂(C),其中,可自由基聚合的化合物(A)的含量为化合物(A)和(B)的总量的5至70重量%。本发明进一步描述了相应的立体光刻应用和方法,以及使用所述发明获得的三维制品。效果:本发明能够获得具有较低表面粗糙度的透明三维制品。10 cl,6 ex,1 tbl

著录项

  • 公开/公告号RU2689578C1

    专利类型

  • 公开/公告日2019-05-28

    原文格式PDF

  • 申请/专利权人 DWS S.R.L.;

    申请/专利号RU2018129215

  • 申请日2017-01-27

  • 分类号G03F7;B29C67;G03F7/038;

  • 国家 RU

  • 入库时间 2022-08-21 11:46:10

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