PDMS-based ligands for quantum dots in silicones

摘要

The invention provides a process for the production of a wavelength converter containing a siloxane polymer matrix with wavelength converter nano particles embedded therein, the process containing (a) mixing (i) a first liquid containing (i1) short chain siloxane polymers and (i2) wavelength converter nano particles having an outer surface grafted with siloxane grafting ligands and (ii) curable siloxane polymers, and (b) curing the curable siloxane polymers, thereby producing the wavelength converter (100); wherein the short chain siloxane polymers have s1 Si backbone elements, wherein the siloxane grafting ligands comprise siloxane grafting ligands having x1 Si backbone elements, wherein at least one Si backbone element of each siloxane grafting ligand comprises a group having a grafting functionality; and wherein the curable siloxane polymers have y1 Si backbone elements, wherein x1/s1≥0.8, s1y1 and wherein x1y1.