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USE OF A SINGLE-COMPONENT LAMINATING ADHESIVE FOR COMPOSITE FILM LAMINATION

机译:使用单组份胶粘剂进行复合膜层压

摘要

A description is given of the use of a one-component laminating adhesive for composite film lamination, and also of a method for composite film lamination. The laminating adhesive comprises an aqueous polymer dispersion preparable by radical emulsion polymerization of monomers comprising (a) at least 60 wt %, based on the total amount of monomers, of at least one monomer selected from the group consisting of C1 to C20 alkyl acrylates, C1 to C20 alkyl methacrylates, vinyl esters of carboxylic acids comprising up to 20 carbon atoms, vinylaromatics having up to 20 carbon atoms, vinyl halides, vinyl ethers of alcohols comprising 1 to 10 carbon atoms, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, and mixtures of these monomers, and (b) at least 0.1 wt %, based on the total amount of monomers, of at least one monomer having at least one acid group, and (c) 0.1 to 5 wt %, based on the total amount of monomers, of at least one ethylenically unsaturated compound having at least one functional group selected from keto groups and aldehyde groups; where the aqueous polymer dispersion comprises at least one compound A which has at least two functional groups that are able to enter into a crosslinking reaction with keto groups or with aldehyde groups; where the molar ratio of the groups of the compound A that are reactive with keto groups or with aldehyde groups to the keto and aldehyde groups of the monomer (b) is from 1:10 to 2:1; and where, in the composite film lamination, at least two films are bonded to one another with the laminating adhesive so firmly that the peel strength is 2.5 N/15 mm or more or that the films bonded to one another are partable only with destruction of at least one of the films. The composite films can be used for the packing of foods.
机译:描述了单组分层压粘合剂用于复合膜层压的用途,以及复合膜层压的方法。所述层压粘合剂包含可通过单体的自由基乳液聚合制备的水性聚合物分散体,所述单体包含(a)基于单体的总量计至少60wt%的至少一种选自丙烯酸C1至C20烷基酯的单体,甲基丙烯酸C1至C20烷基酯,碳原子数不超过20的羧酸乙烯基酯,碳原子数不超过20的乙烯基芳族化合物,卤代乙烯,碳原子数为1至10的醇的乙烯基醚,碳原子数为2至8的脂肪烃和一个或两个双键,以及这些单体的混合物,和(b)以单体的总量计,至少0.1 wt%的至少一种具有至少一个酸基的单体,和(c)0.1至5 wt%基于单体的总量,至少一种具有至少一种选自酮基和醛基的官能团的烯键式不饱和化合物;其中聚合物水分散体包含至少一种化合物A,其具有至少两个能够与酮基或与醛基发生交联反应的官能团;其中与酮基或与醛基反应的化合物A的基团与单体(b)的酮基和醛基的摩尔比为1:10至2:1;并且在复合膜层压中,至少有两层膜用层压粘合剂牢固地粘合在一起,以使剥离强度为2.5 N / 15 mm或更大,或者彼此粘合的膜仅在破坏下才可分开。至少其中一部电影。该复合膜可用于食品包装。

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