首页> 外国专利> METHOD FOR MANUFACTURING ELECTROCONDUCTIVE POLYCARBONATE NANOCOMPOSITE HAVING CABON-BASED FILLER AND ELECTROCONDUCTIVE POLYCARBONATE NANOCOMPOSITE MANUFACTURED THEREBY

METHOD FOR MANUFACTURING ELECTROCONDUCTIVE POLYCARBONATE NANOCOMPOSITE HAVING CABON-BASED FILLER AND ELECTROCONDUCTIVE POLYCARBONATE NANOCOMPOSITE MANUFACTURED THEREBY

机译:具有碳基填充剂的电导性聚碳酸酯纳米复合材料的制备方法及其制备的电导性聚碳酸酯纳米复合材料

摘要

The present invention relates to a method for manufacturing an electroconductive polycarbonate nanocomposite material, comprising the steps of: (a) manufacturing a mixture of 90-99 wt% of a polycarbonate resin and 1-10 wt% of carbon black; (b) manufacturing a composite material composition by mixing 100 parts by weight of the mixture with 1-10 parts by weight of a polyester resin; (c) increasing conductivity of the composite material composition by inducing an ester exchange reaction to the polycarbonate resin and the polyester resin in the composite material composition manufactured in the step (b); and (d) molding the composite material composition obtained in the step (c). According to the present invention, the method for manufacturing an electroconductive polycarbonate nanocomposite material can manufacture a polycarbonate nanocomposite material which can be used for various purposes such as antistatic, electromagnetic wave shielding products, carrier tape, and the like, by adding a polyester resin to a mixture of a polycarbonate resin and carbon black and inducing an ester exchange reaction between polycarbonate and polyester, thereby ensuring electroconductivity. In particular, when polybutylene terephthalate (PBT) is included as a polyester resin, agglomerates of carbon black are destroyed due to high shear stress during injection molding, thereby minimizing a reduction in a conductive path in a composite material, and as a result, suppressing an increase in resistance due to injection molding.
机译:本发明涉及一种制备导电聚碳酸酯纳米复合材料的方法,该方法包括以下步骤:(a)制备90-99重量%的聚碳酸酯树脂和1-10重量%的炭黑的混合物; (b)通过将100重量份的混合物与1-10重量份的聚酯树脂混合来制造复合材料组合物; (c)通过在步骤(b)中制造的复合材料组合物中引起与聚碳酸酯树脂和聚酯树脂的酯交换反应,从而提高复合材料组合物的导电性; (d)模塑步骤(c)中获得的复合材料组合物。根据本发明,用于制造导电聚碳酸酯纳米复合材料的方法可以通过向聚酯树脂中添加聚酯树脂来制造可用于多种目的的聚碳酸酯纳米复合材料,例如抗静电,电磁波屏蔽产品,载带等。聚碳酸酯树脂和炭黑的混合物,并引起聚碳酸酯和聚酯之间的酯交换反应,从而确保导电性。特别地,当包含聚对苯二甲酸丁二酯(PBT)作为聚酯树脂时,由于在注射成型期间的高剪切应力而破坏了炭黑的附聚物,从而使复合材料中的导电路径的减少最小化,并且因此抑制了由于注射成型,电阻增加。

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