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FLUORINE-CONTAINING ETHER COMPOSITION METHOD FOR PRODUCING SAME COATING FLUID AND METHOD FOR MANUFACTURING SUBSTRATE HAVING SURFACE-TREATED LAYER
FLUORINE-CONTAINING ETHER COMPOSITION METHOD FOR PRODUCING SAME COATING FLUID AND METHOD FOR MANUFACTURING SUBSTRATE HAVING SURFACE-TREATED LAYER
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机译:生产含氟涂料的含氟醚组合物的方法和具有表面处理层的基质的制造方法
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摘要
The present invention provides a fluoroether composition capable of imparting good water repellency and oil repellency to the surface of a base material and having excellent friction resistance and not being deteriorated in performance even by repeated rubbing. Ratio of including the AOR F -B, fluorine ether compound B is also more different two kinds represented by, and the proportion of the group, a group (5-1) of the total number of B 90 ~ 95% by mole, based 5-2 Is from 5 to 10 mol%. A is an alkyl group or a perfluoroalkyl carbon number of 1 ~ 6 B. R F is - (CF 2 CF 2 O) b (CF (CF 3) CF 2 O) c (CF 2 O) d (CF 2 CF 2 CF 2 O) e -, and the order of repeating units is not limited. b, c, d and e are each independently an integer of 0 or more, and b + c + d + e is 5 to 150; (5-1): - (CF 2 ) a CFXCH 2 OCH 2 CH 2 CH 2 SiL m R n (5-2): - (CF 2 ) a CFXCH 2 OCH 2 CH (SiL m R n ) CH 3 (5-3): - (CF 2 ) a CFXCH 2 OCH 2 CH = CH 2 (5-4): - (CF 2 ) a CFXCH 2 OCH = CHCH 3 [a is 0 or 1, X is F or CF 3, L is a hydrolyzable group, R is a hydrogen atom or a monovalent hydrocarbon group, m is an integer of 1 ~ 3, n is an integer of 0 ~ 2, m + n = 3]
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机译:本发明提供了一种氟醚组合物,该氟醚组合物能够赋予基材表面良好的拒水性和拒油性,并且具有优异的耐摩擦性并且即使通过反复摩擦也不会使性能劣化。含氟醚化合物B的含AOR F Sup> -B的比例也更不同,以B的总数(90)为基团(5-1)表示两种。以5-2计,约95摩尔%是5至10摩尔%。 A是烷基或全氟烷基碳原子数1〜6B。R F Sup>是-(CF 2 CF 2 O) Sub> b(CF(CF 3)CF 2 O)c(CF 2 O)d(CF 2 CF 2 CF 2 O) e Sub>-,并且重复单元的顺序不受限制。 b,c,d和e分别独立地为0或更大的整数,并且b + c + d + e为5至150。 (5-1):-(CF 2 Sub>) a Sub> CFXCH 2 Sub> OCH 2 Sub> CH 2 < / Sub> CH 2 Sub> SiL m Sub> R n Sub>(5-2):-(CF 2 Sub>)<子> a Sub> CFXCH 2 Sub> OCH 2 Sub> CH(SiL m Sub> R n Sub>)CH 3 Sub>(5-3):-(CF 2 Sub>) a Sub> CFXCH 2 Sub> OCH 2 Sub> CH = CH 2 Sub>(5-4):-(CF 2 Sub>) a Sub> CFXCH 2 Sub> OCH = CHCH 3 Sub> [a为0或1,X为F或CF 3, Sub> L为可水解基团,R为氢原子或一价烃基,m为1的整数。 3,n是0〜2的整数,m + n = 3]
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